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Strategies toward phosphorus-containing PAHs and the effect of P-substitution on the electronic properties

Abstract : In this paper, we report on the different synthetic strategies which led to the preparation of a whole family of polyaromatic hydrocarbons containing a P-atom at the edge. In particular, we show from both experimental and theoretical perspective how the Scholl method has to be adapted to the specificity of organophosphorus derivatives. The P-modified PAHs possess the classical phosphane reactivity that allows fine-tuning of their electronic properties as evidenced by spectro-electrochemistry and theoretical calculations. In particular, the effect of P-substitution on the aromaticity of the different cycles of the PAH was studied.
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Submitted on : Thursday, February 2, 2017 - 4:58:03 PM
Last modification on : Friday, July 10, 2020 - 4:10:37 PM
Long-term archiving on: : Friday, May 5, 2017 - 12:00:32 PM

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Rózsa Szűcs, François Riobé, Aude Escande, Damien Joly, Pierre-Antoine Bouit, et al.. Strategies toward phosphorus-containing PAHs and the effect of P-substitution on the electronic properties. Pure and Applied Chemistry, De Gruyter, 2017, 88 (3), pp.341-356. ⟨10.1515/pac-2016-0909⟩. ⟨hal-01450088⟩

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