Strategies toward phosphorus-containing PAHs and the effect of P-substitution on the electronic properties - Archive ouverte HAL Access content directly
Journal Articles Pure and Applied Chemistry Year : 2017

Strategies toward phosphorus-containing PAHs and the effect of P-substitution on the electronic properties

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Abstract

In this paper, we report on the different synthetic strategies which led to the preparation of a whole family of polyaromatic hydrocarbons containing a P-atom at the edge. In particular, we show from both experimental and theoretical perspective how the Scholl method has to be adapted to the specificity of organophosphorus derivatives. The P-modified PAHs possess the classical phosphane reactivity that allows fine-tuning of their electronic properties as evidenced by spectro-electrochemistry and theoretical calculations. In particular, the effect of P-substitution on the aromaticity of the different cycles of the PAH was studied.
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Dates and versions

hal-01450088 , version 1 (02-02-2017)

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Rózsa Szűcs, François Riobé, Aude Escande, Damien Joly, Pierre-Antoine Bouit, et al.. Strategies toward phosphorus-containing PAHs and the effect of P-substitution on the electronic properties. Pure and Applied Chemistry, 2017, 88 (3), pp.341-356. ⟨10.1515/pac-2016-0909⟩. ⟨hal-01450088⟩
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