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Unexpected isolation and structural characterization of a redox-active Fe(II) piano-stool complex with an η1-dppe ligand

Abstract : A new cationic complex [(η2-bipy)(η5-C5Me5)Fe(η1-dppe)][BPh4] featuring a pendant free diphenylphosphine arm has been isolated in good yield after reaction of 2,2′-bipyridine with the known chloro precursor complex (η2-dppe)(η5-C5Me5)FeCl in presence of NaBPh4. This complex which can be envisioned as a new redox-active building-block has been structurally characterized.
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01468977
Contributor : Laurent Jonchère <>
Submitted on : Thursday, February 16, 2017 - 9:36:07 AM
Last modification on : Saturday, September 19, 2020 - 3:58:47 AM

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Safaa Ibn Ghazala, Frédéric Paul, Loic Toupet, Claude Lapinte. Unexpected isolation and structural characterization of a redox-active Fe(II) piano-stool complex with an η1-dppe ligand. Journal of Organometallic Chemistry, Elsevier, 2007, 692, pp.917-920. ⟨10.1016/j.jorganchem.2006.10.047⟩. ⟨hal-01468977⟩

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