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Structural characterisation of the first mononuclear bismuth porphyrin

Abstract : A single carboxylate picket bismuth porphyrin has been characterised in the solid state as the first instance of a nondimeric structure; the carboxylate picket, bent over the macrocycle, is coordinated to the bismuth, inducing a significant distortion of the porphyrin core.
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01469410
Contributor : Bernard Boitrel <>
Submitted on : Thursday, February 16, 2017 - 2:21:10 PM
Last modification on : Saturday, September 12, 2020 - 3:13:51 AM

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Bernard Boitrel, Zakaria Halime, Lydie Michaudet, Mohamed Lachkar, Loic Toupet. Structural characterisation of the first mononuclear bismuth porphyrin. Chemical Communications, Royal Society of Chemistry, 2003, pp.2670-2671. ⟨10.1039/b309615g⟩. ⟨hal-01469410⟩

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