(Methanol){α-5,10,15:β-20-tetrakis[2-(chloroacetamido)phenyl]porphyrin}zinc(II) chloroform solvate

David Ricard (1) , Philippe Richard (2) , Bernard Boitrel (2)

1 ISCR - Institut des Sciences Chimiques de Rennes
2 ICMUB - Institut de Chimie Moléculaire de l'Université de Bourgogne [Dijon]

The pentacoordinated Zn atom in the title compound, [Zn(C52H36Cl4N8O4)(CH4O)].CHCl3, is displaced from the porphyrin N4 plane towards the axial methanol ligand by 0.269 (2) Å . The average Zn-N(porphyrin) distance is 2.063 (9) Å and the axial Zn-O(MeOH) distance is 2.147 (5) Å.

Domains: Chemical Sciences

David Ricard, Philippe Richard, Bernard Boitrel. (Methanol){α-5,10,15:β-20-tetrakis[2-(chloroacetamido)phenyl]porphyrin}zinc(II) chloroform solvate. Acta Crystallographica Section E : Structure Reports Online [2001-2014], 2001, 57 (9), pp.m404 - m406. ⟨10.1107/S1600536801012788⟩. ⟨hal-01469431⟩