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(Methanol){α-5,10,15:β-20-tetrakis[2-(chloroacetamido)phenyl]porphyrin}zinc(II) chloroform solvate

Abstract : The pentacoordinated Zn atom in the title compound, [Zn(C52H36Cl4N8O4)(CH4O)].CHCl3, is displaced from the porphyrin N4 plane towards the axial methanol ligand by 0.269 (2) Å . The average Zn-N(porphyrin) distance is 2.063 (9) Å and the axial Zn-O(MeOH) distance is 2.147 (5) Å.
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01469431
Contributor : Bernard Boitrel <>
Submitted on : Thursday, February 16, 2017 - 2:35:21 PM
Last modification on : Thursday, March 5, 2020 - 2:05:49 PM

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David Ricard, Philippe Richard, Bernard Boitrel. (Methanol){α-5,10,15:β-20-tetrakis[2-(chloroacetamido)phenyl]porphyrin}zinc(II) chloroform solvate. Acta Crystallographica Section E: Structure Reports Online, International Union of Crystallography, 2001, 57 (9), pp.m404 - m406. ⟨10.1107/S1600536801012788⟩. ⟨hal-01469431⟩

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