Synthesis and crystal structure of an unprecedented bismuth porphyrin containing ester pendant arms

Lydie Michaudet (1) , Philippe Richard (1) , Bernard Boitrel (1)

1 LSEO - Laboratoire de synthèse et d'électrosynthèse organométallique [Dijon]

An easily prepared porphyrin with pendant arms is shown to form a stable complex with bismuth(III) ion; the complex is eight coordinate with a square antiprismatic coordination geometry; the solid-state structure exhibits the formation of a dimer assembled via mutual coordination of a terminal ester group.

Domaines: Chimie

Lydie Michaudet, Philippe Richard, Bernard Boitrel. Synthesis and crystal structure of an unprecedented bismuth porphyrin containing ester pendant arms. Chemical Communications, 2000, 17, pp.1589 - 1590. ⟨10.1039/b004394j⟩. ⟨hal-01469438⟩