Synthesis of a new bis-pyridyl crown-capped porphyrin

Bernard Boitrel (1) , Christian Ruzié (2) , Lydie Michaudet (2)

1 OCCEM - Organométalliques et catalyse : chimie et électrochimie moléculaires
2 ICMUB - Institut de Chimie Moléculaire de l'Université de Bourgogne [Dijon]

The synthesis of a new porphyrin bearing both two pyridyl residues and two ortho-nitrophenyl groups in meso position is reported. The reduction of the nitro functions provides the points of anchoring for a crown ether maintained in a cofacial conformation. The synthesis of a new porphyrin bearing both two pyridyl residues and two ortho-nitrophenyl groups in meso position is reported. The reduction of the nitro functions provide the points of anchoring for a crown ether maintained in a cofacial conformation.

Domaines: Chimie

Bernard Boitrel, Christian Ruzié, Lydie Michaudet. Synthesis of a new bis-pyridyl crown-capped porphyrin. Tetrahedron Letters, 2002, 43 (41), pp.7423-7426. ⟨10.1016/S0040-4039(02)01659-3⟩. ⟨hal-01469515⟩