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A Versatile and Convenient Method for the Functionalization of Porphyrins

Bernard Boitrel 1 Amandine Didier 1 Lydie Michaudet 1 David Ricard 1 Valérie Baveux-Chambenoît 1 Philippe Richard 1
1 ICMUB - Institut de Chimie Moléculaire de l'Université de Bourgogne [Dijon]
Abstract : The condensation of 3-(chloromethyl)benzoyl chloride with different atropisomers of meso-(tetra-o-aminophenyl)porphyrin (TAPP), followed by the reaction of a series of nucleophilic reagents leads, among others, to precursors of biomimetic models of heme proteins such as cytochrome c oxidase (CcO). This synthesis can also be applied as an efficient two-step reaction to obtain highly functionalized porphyrin derivatives potentially useful for cation binding.
Keywords : Porphyrins Oxidoreductases Heme proteins Enzyme models Cations
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Journal articles
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01469583
Contributor : Bernard Boitrel <>
Submitted on : Thursday, February 16, 2017 - 3:34:37 PM
Last modification on : Friday, June 8, 2018 - 2:50:12 PM

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  • HAL Id : hal-01469583, version 1

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UNIV-RENNES1 | CNRS | UNIV-BOURGOGNE | INC-CNRS | ICMUB | UNIV-RENNES

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Bernard Boitrel, Amandine Didier, Lydie Michaudet, David Ricard, Valérie Baveux-Chambenoît, et al.. A Versatile and Convenient Method for the Functionalization of Porphyrins. European Journal of Organic Chemistry, Wiley-VCH Verlag, 2001, 10, pp.1917-1926. ⟨hal-01469583⟩

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