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Journal Articles European Journal of Organic Chemistry Year : 2001

A Versatile and Convenient Method for the Functionalization of Porphyrins

Abstract

The condensation of 3-(chloromethyl)benzoyl chloride with different atropisomers of meso-(tetra-o-aminophenyl)porphyrin (TAPP), followed by the reaction of a series of nucleophilic reagents leads, among others, to precursors of biomimetic models of heme proteins such as cytochrome c oxidase (CcO). This synthesis can also be applied as an efficient two-step reaction to obtain highly functionalized porphyrin derivatives potentially useful for cation binding.

Dates and versions

hal-01469583 , version 1 (16-02-2017)

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Bernard Boitrel, Amandine Didier, Lydie Michaudet, David Ricard, Valérie Baveux-Chambenoît, et al.. A Versatile and Convenient Method for the Functionalization of Porphyrins. European Journal of Organic Chemistry, 2001, 10, pp.1917-1926. ⟨10.1002/1099-0690(200105)2001:10<1927::AID-EJOC1917>3.0.CO;2-5⟩. ⟨hal-01469583⟩
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