Electrocatalytic reduction of dioxygen to water by tren-capped porphyrins, functional models of cytochrome c oxidase - Archive ouverte HAL Access content directly
Journal Articles Chemical Communications Year : 1999

Electrocatalytic reduction of dioxygen to water by tren-capped porphyrins, functional models of cytochrome c oxidase

Abstract

Two different tren-capped porphyrins—in which the two metals, iron and copper, are more or less off-centered—are shown to be efficient catalysts for the reduction of O2 to H2O; surprisingly, their iron-only complexes are shown to be even more effective 4e- catalysts when adsorbed on a graphite electrode.
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Dates and versions

hal-01469599 , version 1 (16-02-2017)

Identifiers

  • HAL Id : hal-01469599 , version 1

Cite

Bernard Boitrel, David Ricard, Andrioletti Bruno, Maurice L'Her. Electrocatalytic reduction of dioxygen to water by tren-capped porphyrins, functional models of cytochrome c oxidase. Chemical Communications, 1999, 16, pp.1523-1524. ⟨hal-01469599⟩
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