High affinity of "arbor" iron porphyrins for dioxygen

Bernard Boitrel (1) , David Ricard (1) , Andrioletti Bruno (1) , Roger Guilard (1)

1 LSEO - Laboratoire de synthèse et d'électrosynthèse organométallique [Dijon]

The equilibrium rates of dioxygen and carbon monoxide binding have been measured for a series of capped iron porphyrins called "arbor". The affinity for dioxygen of these models is 100-fold higher than the highest previously reported values.

Domains: Chemical Sciences

Bernard Boitrel, David Ricard, Andrioletti Bruno, Roger Guilard. High affinity of "arbor" iron porphyrins for dioxygen. New Journal of Chemistry, 1998, 22 (12), pp.1331-1332. ⟨10.1039/a805357j⟩. ⟨hal-01469622⟩