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Grafting cyclams or related compounds over a porphyrin

Abstract : The synthesis and characterization of several new polymacrocycles containing a porphyrin and one or two cyclam units are described. The use of 1,8-ditertbutyloxycarbonyl cyclam (1,8-diBoc-cyclam) led to new biomimetic models in good yields. In order to tune the distance between the macrocycles, two different linkers were successively used. Such a method might promote a bimetallic interaction between the two corresponding complexes.
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01469675
Contributor : Bernard Boitrel <>
Submitted on : Thursday, February 16, 2017 - 4:24:45 PM
Last modification on : Friday, June 8, 2018 - 2:50:12 PM

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  • HAL Id : hal-01469675, version 1

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Bernard Boitrel, Andrioletti Bruno, Roger Guilard. Grafting cyclams or related compounds over a porphyrin. Comptes rendus de l’Académie des sciences. Série IIb, Mécanique, physique, chimie, astronomie, Elsevier, 1996, 323 (12), pp.859-864. ⟨hal-01469675⟩

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