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Grafting cyclams or related compounds over a porphyrin

Abstract : The synthesis and characterization of several new polymacrocycles containing a porphyrin and one or two cyclam units are described. The use of 1,8-ditertbutyloxycarbonyl cyclam (1,8-diBoc-cyclam) led to new biomimetic models in good yields. In order to tune the distance between the macrocycles, two different linkers were successively used. Such a method might promote a bimetallic interaction between the two corresponding complexes.
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  • HAL Id : hal-01469675, version 1


Bernard Boitrel, Andrioletti Bruno, Roger Guilard. Grafting cyclams or related compounds over a porphyrin. Comptes rendus de l’Académie des sciences. Série IIb, Mécanique, physique, chimie, astronomie, Elsevier, 1996, 323 (12), pp.859-864. ⟨hal-01469675⟩



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