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Journal articles
O2 and CO Binding to Tetraaza-Tripodal-Capped Iron(II) Porphyrins
Abstract : A series of tris(2-aminoethylamine) (tren) capped iron(II) porphyrins has been synthesized and characterized and their affinities for dioxygen and carbon monoxide measured. The X-ray structure of the basic scaffold with nickel inserted in the porphyrin is also reported. All the ligands differ by the nature of the group(s) attached to the secondary amine functions of the cap. These various substitutions were introduced to probe if a hydrogen bond
with these secondary amine groups acting as the donor could rationalize the high affinity of these myoglobin models. This work clearly indicates that the cage structure of the tren predominates over all the other appended groups with the exception of p-nitrophenol.
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01470255
Contributor : Bernard Boitrel <>
Submitted on : Friday, February 17, 2017 - 11:15:09 AM
Last modification on : Tuesday, January 12, 2021 - 4:46:22 PM
Contributor : Bernard Boitrel <>
Submitted on : Friday, February 17, 2017 - 11:15:09 AM
Last modification on : Tuesday, January 12, 2021 - 4:46:22 PM
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