Skip to Main content Skip to Navigation
Journal articles

Electron Transfer and Modification of Oligosilanylsilatranes and Related Derivatives

Abstract : Several silatranyl -substituted oligosilanes were prepared starting from bis(trimethylsilyl)silatranylsilanide. Electrochemical and theoretical investigations of some oligosilanes revealed that electrooxidation occurs by formation of a short-lived cation radical. This species undergoes structural relaxation to form a pair of conformers, with endo and exo relationships with respect to the Si-N interaction. Reaction of a 1,4-disilatranyl-1,4-disilanide with 1,2-dichlorotetramethyldisilane gave a mixture of cis and trans diastereomers of a cyclohexasilane with the trans isomer showing a diminished Si-N distance.
Document type :
Journal articles
Complete list of metadata
Contributor : Laurent Jonchère Connect in order to contact the contributor
Submitted on : Friday, February 17, 2017 - 2:41:41 PM
Last modification on : Thursday, May 19, 2022 - 2:16:07 PM

Links full text



Mohammad Aghazadeh Meshgi, Judith Baumgartner, Viatcheslav V. Jouikov, Christoph Marschner. Electron Transfer and Modification of Oligosilanylsilatranes and Related Derivatives. Organometallics, American Chemical Society, 2017, 36 (2), pp.342-351. ⟨10.1021/acs.organomet.6b00786⟩. ⟨hal-01470479⟩



Record views