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Confining Phosphanes Derived from Cyclodextrins for Efficient Regio- and Enantioselective Hydroformylation

Matthieu Jouffroy 1 Rafael Gramage-Doria 1 Dominique Armspach 1 David Semeril 1 Werner Oberhauser 2 Dominique Matt 1 Loic Toupet 3
1 Institut de Chimie de Strasbourg
2 ICCOM - Istituto di Chimica dei Composti Organometallici
3 GMCM - Groupe matière condensée et matériaux
Abstract : Two confining phosphane ligands derived from either a-or b-cyclodextrin produce singly P III-ligated metal complexes with unusual coordination spheres. High-pressure NMR studies have revealed that rhodium hydride complexes of the same type are also formed under hydroformylation conditions. This unique feature strongly favors the formation of the branched aldehyde at the expense of the linear one with high enantioselectivity in the rhodium-catalyzed hydroformy-lation of styrene.
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01472887
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Submitted on : Tuesday, February 21, 2017 - 2:26:21 PM
Last modification on : Tuesday, December 7, 2021 - 12:22:06 PM

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Matthieu Jouffroy, Rafael Gramage-Doria, Dominique Armspach, David Semeril, Werner Oberhauser, et al.. Confining Phosphanes Derived from Cyclodextrins for Efficient Regio- and Enantioselective Hydroformylation. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2014, 53, pp.3937 - 3940. ⟨10.1002/anie.201311291⟩. ⟨hal-01472887⟩

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