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Supramolecular Ligands in Gold(I) Catalysis

Abstract : Golden (I): A supramolecular ligand–template strategy is applied to gold(I) catalysis. The supramolecular ligands, formed from a phosphoramidite backbone and two templates, display different regioselectivity in the hydroalkoxylation of allenes compared to non-supramolecular analogues. Based on these findings, the catalytic activity of gold(I) complexes could be tunable at a supramolecular level.
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01472911
Contributor : Rafael Gramage-Doria <>
Submitted on : Tuesday, February 21, 2017 - 2:41:44 PM
Last modification on : Tuesday, March 10, 2020 - 12:44:03 PM

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Rafael Gramage-Doria, Rosalba Bellini, Jeroen Rintjema, Joost N. H. Reek. Supramolecular Ligands in Gold(I) Catalysis. ChemCatChem, Wiley, 2012, 5 (5), pp.1084 - 1087. ⟨10.1002/cctc.201200541⟩. ⟨hal-01472911⟩

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