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Remotely Controlled Iridium-Catalyzed Asymmetric Hydrogenation of Terminal 1,1-Diaryl Alkenes

Abstract : Working together: The presence of a remote directing group on terminal 1,1-diaryl and 1,1-dialkyl alkenes led to high and unprecedented enantioselectivity in iridium-catalyzed asymmetric hydrogenation (see scheme). This strategy offers efficient synthetic pathways towards valuable enantiomerically enriched 1,1-diaryl and 1,1-dialkyl alkanes. Moreover, the directing group can be further functionalized.
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01472915
Contributor : Rafael Gramage-Doria <>
Submitted on : Tuesday, February 21, 2017 - 2:43:23 PM
Last modification on : Tuesday, November 3, 2020 - 9:50:05 AM

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Tatiana Besset, Rafael Gramage-Doria, Joost N. H. Reek. Remotely Controlled Iridium-Catalyzed Asymmetric Hydrogenation of Terminal 1,1-Diaryl Alkenes. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2013, 52, pp.8795 - 8797. ⟨10.1002/anie.201302942⟩. ⟨hal-01472915⟩

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