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A Cavity-Shaped Diphosphane Displaying " Oschelating " Behavior**

Abstract : A molecular balance wheel: Transition metals form β-cyclodextrin-derived diphosphane chelate complexes (picture: ligand structure) in which a fast oscillatory motion about the metal ion takes place (“oschelating behavior”). The observed movement occurs without dissociation of the metal–phosphorus bond.
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01472929
Contributor : Rafael Gramage-Doria <>
Submitted on : Tuesday, February 21, 2017 - 2:52:03 PM
Last modification on : Tuesday, November 3, 2020 - 9:50:05 AM

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Rafael Gramage-Doria, Dominique Armspach, Dominique Matt, Loic Toupet. A Cavity-Shaped Diphosphane Displaying " Oschelating " Behavior**. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2011, 50 (7), pp.1554-1559. ⟨10.1002/anie.201005169⟩. ⟨hal-01472929⟩

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