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Journal Articles Angewandte Chemie International Edition Year : 2011

A Cavity-Shaped Diphosphane Displaying “Oschelating” Behavior


A molecular balance wheel: transition metals form with a β-cyclodextrin-derived diphosphane chelate complexes in which a fast oscillatory motion about the metal ion takes place. The observed movement occurs without metal-phosphorus bond dissociation.
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hal-01472929 , version 1 (30-11-2020)



Rafael Gramage-Doria, Dominique Armspach, Dominique Matt, Loic Toupet. A Cavity-Shaped Diphosphane Displaying “Oschelating” Behavior. Angewandte Chemie International Edition, 2011, 50 (7), pp.1554-1559. ⟨10.1002/anie.201005169⟩. ⟨hal-01472929⟩
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