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Ruthenium-allenylidene complexes and their specific behaviour

Abstract : This review presents recent innovations in the field of stoichiometric transformations of ruthenium-allenylidene systems via synthesis and at the frontier of material science and catalysis. It especially shows new routes to the first bis-allenylidene-ruthenium and diruthenium complexes, trisallenylidene ruthenium triskelia, the use of ruthenium-allenylidene as precursors for alkenylcarbynes and indenylidenes, and the involvement of allenylidenes in the building of dinuclear ruthenium bridges with a C-7 carbon-rich bridge. (C) 2004 Elsevier B.V. All rights reserved.
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Stéphane Rigaut, D Touchard, Ph Dixneuf. Ruthenium-allenylidene complexes and their specific behaviour. Coordination Chemistry Reviews, Elsevier, 2004, 248 (15-16), pp.1585--1601. ⟨10.1016/j.ccr.2004.04.016⟩. ⟨hal-01475056⟩



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