Skip to Main content Skip to Navigation
Journal articles

A new binuclear ruthenium complex with an annelated C-7 bridge via an unprecedented [2+2] coupling reaction

Abstract : Treatment of [Cl(dppe)(2)Ru-C=C-C=C-SiMe3] with [Fe(C5H5)(2)]PF6 leads to an unprecedented metal-assisted[2 + 2] coupling reaction on C-gamma=C-delta bonds to obtain [Cl(dppe)(2)Ru-C=C-C=CHC(CH2)=C=C=Ru(dppe)(2)Cl]PF6 with the charge highly delocalized over seven carbon atoms and including a cyclobutenyl bridge; the crystal structure was solved.
Document type :
Journal articles
Complete list of metadatas

https://hal-univ-rennes1.archives-ouvertes.fr/hal-01475064
Contributor : Stéphane Rigaut <>
Submitted on : Thursday, February 23, 2017 - 2:29:31 PM
Last modification on : Thursday, November 21, 2019 - 2:06:52 AM

Links full text

Identifiers

Citation

Stéphane Rigaut, L Le Pichon, Jc Daran, D Touchard, Ph Dixneuf. A new binuclear ruthenium complex with an annelated C-7 bridge via an unprecedented [2+2] coupling reaction. Chemical Communications, Royal Society of Chemistry, 2001, pp.1206--1207. ⟨10.1039/b103301h⟩. ⟨hal-01475064⟩

Share

Metrics

Record views

128