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Journal articles
A new binuclear ruthenium complex with an annelated C-7 bridge via an unprecedented [2+2] coupling reaction
Abstract : Treatment of [Cl(dppe)(2)Ru-C=C-C=C-SiMe3] with [Fe(C5H5)(2)]PF6 leads to an unprecedented metal-assisted[2 + 2] coupling reaction on C-gamma=C-delta bonds to obtain [Cl(dppe)(2)Ru-C=C-C=CHC(CH2)=C=C=Ru(dppe)(2)Cl]PF6 with the charge highly delocalized over seven carbon atoms and including a cyclobutenyl bridge; the crystal structure was solved.
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01475064
Contributor : Stéphane Rigaut <>
Submitted on : Thursday, February 23, 2017 - 2:29:31 PM
Last modification on : Thursday, November 21, 2019 - 2:06:52 AM
Contributor : Stéphane Rigaut <>
Submitted on : Thursday, February 23, 2017 - 2:29:31 PM
Last modification on : Thursday, November 21, 2019 - 2:06:52 AM
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