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Electron-reservoir Fe-I complexes: Multiple applications as electron-transfer reagents and the extraordinary reactivity of superoxide generated from dioxygen

Abstract : The electron-transfer properties of electron-reservoir Fe-I sandwich complexes are briefly reviewed, with emphasis on their ability to generate extremely reactive superoxide radical anion. These electron-transfer processes include (i) stoichiometric electron-transfer reactions to a variety of substrates, (ii) redox catalysis, (iii) initiation of electron-transfer-chain catalyzed processes, (iv) sensors in dendrimers for molecular recognition and (v) new, solvent- and medium-independent references for the determination of electrochemical redox potentials.
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01475068
Contributor : Stéphane Rigaut <>
Submitted on : Thursday, February 23, 2017 - 2:29:39 PM
Last modification on : Monday, March 26, 2018 - 3:23:44 PM

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D Astruc, Stéphane Rigaut, E Alonso, C Valerio, Mh Delville, et al.. Electron-reservoir Fe-I complexes: Multiple applications as electron-transfer reagents and the extraordinary reactivity of superoxide generated from dioxygen. ACH-MODELS IN CHEMISTRY, 1998, 135 (5), pp.751--769. ⟨hal-01475068⟩

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