Electron-reservoir Fe-I complexes: Multiple applications as electron-transfer reagents and the extraordinary reactivity of superoxide generated from dioxygen - Archive ouverte HAL Access content directly
Journal Articles ACH-MODELS IN CHEMISTRY Year : 1998

Electron-reservoir Fe-I complexes: Multiple applications as electron-transfer reagents and the extraordinary reactivity of superoxide generated from dioxygen

Stéphane Rigaut
E Alonso
  • Function : Author
C Valerio
  • Function : Author
Mh Delville
  • Function : Author
J Ruiz
  • Function : Author

Abstract

The electron-transfer properties of electron-reservoir Fe-I sandwich complexes are briefly reviewed, with emphasis on their ability to generate extremely reactive superoxide radical anion. These electron-transfer processes include (i) stoichiometric electron-transfer reactions to a variety of substrates, (ii) redox catalysis, (iii) initiation of electron-transfer-chain catalyzed processes, (iv) sensors in dendrimers for molecular recognition and (v) new, solvent- and medium-independent references for the determination of electrochemical redox potentials.
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hal-01475068 , version 1 (23-02-2017)

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  • HAL Id : hal-01475068 , version 1

Cite

D Astruc, Stéphane Rigaut, E Alonso, C Valerio, Mh Delville, et al.. Electron-reservoir Fe-I complexes: Multiple applications as electron-transfer reagents and the extraordinary reactivity of superoxide generated from dioxygen. ACH-MODELS IN CHEMISTRY, 1998, 135 (5), pp.751--769. ⟨hal-01475068⟩
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