1-ELECTRON, 2-ELECTRON AND 3-ELECTRON REDUCTION OF C-60 USING THE ELECTRON-RESERVOIR COMPLEX [FE(1)(C5H5)(C6ME6)]

C Bossard (1) , Stéphane Rigaut , D Astruc , Mh Delville , G Felix , A Fevrierbouvier , J Amiell , S Flandrois , P Delhaes

1 CRPP - Centre de recherches Paul Pascal

The reaction between the 19-electron complex [FeI(C5H5)(C6Me6)] 1 and C60 in toluene gives the paramagnetic salts (1+)C60-, (1+)C-2(60)2- and (1+)C-3(60)3- depending on the stoichiometry of the reactants

Domaines: Chimie

C Bossard, Stéphane Rigaut, D Astruc, Mh Delville, G Felix, et al.. 1-ELECTRON, 2-ELECTRON AND 3-ELECTRON REDUCTION OF C-60 USING THE ELECTRON-RESERVOIR COMPLEX [FE(1)(C5H5)(C6ME6)]. Journal of the Chemical Society, Chemical Communications, 1993, 3, pp.333--334. ⟨10.1039/c39930000333⟩. ⟨hal-01475072⟩