Chiral 1,2-dithiine as a sulfur rich electron acceptor

Yann Le Gal (1) , Dorine Ameline (1) , Antoine Vacher (1) , Thierry Roisnel (1) , Vincent Dorcet (1) , Dominique Lorcy (1)

1 ISCR - Institut des Sciences Chimiques de Rennes

The selective synthesis of both enantiomers of a Sulfur rich electron acceptor containing two 1-phenylethyl groups of the same chirality and a chiral axis is described. Cyclisation into enantiopure dithiine has been induced by the presence of a chiral substituent on the nitrogen atom of a thiazoline-2-thione dithiolate precursor.

Keywords: complexes; disulfides

Domains: Chemical Sciences

Yann Le Gal, Dorine Ameline, Antoine Vacher, Thierry Roisnel, Vincent Dorcet, et al.. Chiral 1,2-dithiine as a sulfur rich electron acceptor. New Journal of Chemistry, 2016, 40 (12), pp.9930--9935. ⟨10.1039/c6nj02292h⟩. ⟨hal-01475467⟩