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Chiral 1,2-dithiine as a sulfur rich electron acceptor

Abstract : The selective synthesis of both enantiomers of a Sulfur rich electron acceptor containing two 1-phenylethyl groups of the same chirality and a chiral axis is described. Cyclisation into enantiopure dithiine has been induced by the presence of a chiral substituent on the nitrogen atom of a thiazoline-2-thione dithiolate precursor.
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Yann Le Gal, Dorine Ameline, Antoine Vacher, Thierry Roisnel, Vincent Dorcet, et al.. Chiral 1,2-dithiine as a sulfur rich electron acceptor. New Journal of Chemistry, Royal Society of Chemistry, 2016, 40 (12), pp.9930--9935. ⟨10.1039/c6nj02292h⟩. ⟨hal-01475467⟩

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