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Hydrogenation of ketones with a manganese PN3P pincer pre-catalyst

Abstract : A catalytic hydrogenation of carbonyl derivs. with a manganese pre-catalyst has been developed. The key feature is the use of an air stable cationic manganese pre-catalyst bearing a tridendate ligand with a 2,6-(diaminopyridinyl)diphosphine scaffold. Under 50 bar of H2, at 130°, various ketones were reduced to the corresponding alcs. with moderate to good yield.
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01475820
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Submitted on : Friday, February 24, 2017 - 11:07:15 AM
Last modification on : Thursday, March 5, 2020 - 2:02:54 PM

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Antoine Bruneau-Voisine, Ding Wang, Thierry Roisnel, Christophe Darcel, Jean-Baptiste Sortais. Hydrogenation of ketones with a manganese PN3P pincer pre-catalyst. Catalysis Communications, Elsevier, 2017, 92, pp.1-4. ⟨10.1016/j.catcom.2016.12.017⟩. ⟨hal-01475820⟩

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