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Journal articles
Correlating Structure with Threshold Behavior of Chalcogenide Glasses Within Ge-Sn-Se Ternary System
Abstract : A systematic investigation of the optical and structural properties of chalcogenide glasses in Ge-Sn-Se ternary system is presented. We have found a threshold behavior of optical property, namely, existence of transitional composition of the Ge-Sn-Se glasses, with progressive replacement of Se by Sn. Calculation of mean coordination number indicates that the transition-like feature of optical property is associated with the evolution of chemical ordering of the Ge-Sn-Se network. Analysis of Raman spectra of the glasses explains that the interaction between Se-Se bonds, Sn(Se-1/2)(4) tetrahedra, and Sn-Sn homopolar bonds is the origination of such optical phenomenon.
Cited literature [25 references]
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01500401
Contributor : Laurent Jonchère <>
Submitted on : Tuesday, May 23, 2017 - 10:31:48 AM
Last modification on : Wednesday, April 7, 2021 - 3:18:09 PM
Long-term archiving on: : Friday, August 25, 2017 - 12:49:04 AM
Contributor : Laurent Jonchère <>
Submitted on : Tuesday, May 23, 2017 - 10:31:48 AM
Last modification on : Wednesday, April 7, 2021 - 3:18:09 PM
Long-term archiving on: : Friday, August 25, 2017 - 12:49:04 AM
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Correlating structure with thr...
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