Skip to Main content Skip to Navigation
Journal articles

Slow Magnetic Relaxation in Chiral Helicene-Based Coordination Complex of Dysprosium

Abstract : The complex [Dy(L)(tta)(3)] with L the chiral 3-(2-pyridyl)-4-aza[6]-helicene ligand (tta(-) = 2-thenoyltrifluoroaacetonate) has been synthesized in its racemic form and structurally and magnetically characterized. [Dy(L)(tta)(3)] behaves as a single molecule magnet in its crystalline phase with the opening of a hysteresis loop at 0.50 K. These magnetic properties were interpreted with ab initio calculations.
Document type :
Journal articles
Complete list of metadatas

https://hal-univ-rennes1.archives-ouvertes.fr/hal-01500406
Contributor : Laurent Jonchère <>
Submitted on : Monday, April 3, 2017 - 11:15:03 AM
Last modification on : Friday, July 10, 2020 - 4:20:19 PM

Links full text

Identifiers

Citation

Guglielmo Fernandez-Garcia, Jessica Flores Gonzalez, Jiang-Kun Ou-Yang, Nidal Saleh, Fabrice Pointillart, et al.. Slow Magnetic Relaxation in Chiral Helicene-Based Coordination Complex of Dysprosium. Magnetochemistry, MDPI, 2017, 3 (1), ⟨10.3390/magnetochemistry3010002⟩. ⟨hal-01500406⟩

Share

Metrics

Record views

292