Improved and General Manganese-Catalyzed N-Methylation of Aromatic Amines Using Methanol

Jacob Neumann; Saravanakumar Elangovan; Anke Spannenberg; Kathrin Junge; Matthias Beller

doi:10.1002/chem.201605218

Journal articles

Improved and General Manganese-Catalyzed N-Methylation of Aromatic Amines Using Methanol

Jacob Neumann ¹ Saravanakumar Elangovan ^{2, 1} Anke Spannenberg ¹ Kathrin Junge ¹ Matthias Beller ¹

1 LIKAT Rostock - Leibniz-Institut für Katalyse

2 ISCR - Institut des Sciences Chimiques de Rennes

Abstract : A novel lutidine-based manganese PNP-pincer complex has been synthesized for the selective N-methylation of aromatic amines with methanol. Using borrowing hydrogen methodology, a selection of differently functionalized aniline derivatives is selectively methylated in good yields.

Keywords : manganese amines borrowing hydrogen pincer complex methylation

Document type :

Journal articles

Domain :

Chemical Sciences

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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01518033
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Submitted on : Thursday, May 4, 2017 - 10:31:08 AM
Last modification on : Tuesday, January 12, 2021 - 4:40:56 PM

Improved and General Manganese-Catalyzed N-Methylation of Aromatic Amines Using Methanol

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Improved and General Manganese-Catalyzed N-Methylation of Aromatic Amines Using Methanol

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