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Engineering of Syndiotactic and Isotactic Polystyrene-Based Copolymers via Stereoselective Catalytic Polymerization

Abstract : This contribution presents an updated overview of the different copolymers containing stereoregular polystyrene blocks. Special emphasis is placed on syndiospecific and isospecific copolymerization of styrene with co-monomers (ethylene and α-olefins, conjugated and non-conjugated dienes, styrene derivatives, etc.). The catalytic systems involved are described and the polymerization mechanisms are discussed. Alternative approaches (simultaneous, living, chain-transfer and graft copolymerization) and the resulting detailed structures and characteristics of the copolymers are also reported.
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01518043
Contributor : Laurent Jonchère <>
Submitted on : Thursday, May 4, 2017 - 10:31:18 AM
Last modification on : Thursday, March 5, 2020 - 2:05:45 PM

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Eva Laur, Evgueni Kirillov, Jean-François Carpentier. Engineering of Syndiotactic and Isotactic Polystyrene-Based Copolymers via Stereoselective Catalytic Polymerization. Molecules, MDPI, 2017, 22 (4), ⟨10.3390/molecules22040594⟩. ⟨hal-01518043⟩

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