A Triflamide-Tethered N-Heterocyclic Carbene-Rhodium(I) Catalyst for Hydroalkoxylation Reactions: Ligand-Promoted Nucleophilic Activation of Alcohols
Abstract
A triflamide-tethered N-heterocyclic carbene (NHC)-bound Rh-I dicarbonyl catalyst was highly effective for both intermolecular hydroalkoxylation and intramolecular heteroannulation reactions. The involvement of both the amido nitrogen and triflato oxygen atoms of the triflamide functionality for alcohol activation and 1,2-hydrogen shift, respectively, was proposed.
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Bera et al. - 2017 - A Triflamide-tethered NHC‒Rh(I) Catalyst for Hydro.pdf (607.55 Ko)
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cctc201601667-sup-0001-misc_information.pdf (2.23 Mo)
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Origin : Files produced by the author(s)
Origin : Files produced by the author(s)
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