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A Triflamide-Tethered N-Heterocyclic Carbene-Rhodium(I) Catalyst for Hydroalkoxylation Reactions: Ligand-Promoted Nucleophilic Activation of Alcohols

Abstract : A triflamide-tethered N-heterocyclic carbene (NHC)-bound Rh-I dicarbonyl catalyst was highly effective for both intermolecular hydroalkoxylation and intramolecular heteroannulation reactions. The involvement of both the amido nitrogen and triflato oxygen atoms of the triflamide functionality for alcohol activation and 1,2-hydrogen shift, respectively, was proposed.
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01532168
Contributor : Laurent Jonchère <>
Submitted on : Tuesday, July 4, 2017 - 11:38:21 AM
Last modification on : Friday, July 10, 2020 - 4:14:26 PM

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Abir Sarbajna, Pragati Pandey, S. M. Wahidur Rahaman, Kuldeep Singh, Akshi Tyagi, et al.. A Triflamide-Tethered N-Heterocyclic Carbene-Rhodium(I) Catalyst for Hydroalkoxylation Reactions: Ligand-Promoted Nucleophilic Activation of Alcohols. ChemCatChem, Wiley, 2017, 9 (8), pp.1397-1401. ⟨10.1002/cctc.201601667⟩. ⟨hal-01532168⟩

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