Skip to Main content Skip to Navigation
Journal articles

Total Synthesis of γ-Indomycinone and Kidamycinone by Means of Two Regioselective Diels-Alder Reactions

Abstract : An efficient access for the synthesis of pluramycinones is described. Total syntheses of racemic γ-indomycinone and kidamycinone were achieved by means of two Diels-Alder reactions. A first Diels-Alder condensation followed by a Stille cross-coupling is used for the elaboration of the desired substituted dienes which will be involved in the second pericyclic reaction with juglone to construct the tetracyclic core of pluramycinones.
Document type :
Journal articles
Complete list of metadatas

https://hal-univ-rennes1.archives-ouvertes.fr/hal-01533331
Contributor : Laurent Jonchère <>
Submitted on : Tuesday, June 6, 2017 - 12:12:02 PM
Last modification on : Wednesday, March 25, 2020 - 9:20:52 AM
Long-term archiving on: : Monday, January 22, 2018 - 10:54:21 PM

Identifiers

Citation

Thibaud Mabit, Aymeric Siard, Mathilde Pantin, Doumadé Zon, Laura Foulgoc, et al.. Total Synthesis of γ-Indomycinone and Kidamycinone by Means of Two Regioselective Diels-Alder Reactions. Journal of Organic Chemistry, American Chemical Society, 2017, 82 (11), pp.5710-5719. ⟨10.1021/acs.joc.7b00544⟩. ⟨hal-01533331⟩

Share

Metrics

Record views

546

Files downloads

786