Reactivity of Functionalized Ynamides with Tetracyanoethylene: Scope, Limitations and Optoelectronic Properties of the Adducts

Abstract : The reactivity of functionalized ynamides and arylynamines with tetracyanoethylene at room temperature was evaluated. In most cases, the corresponding 1,1,4,4-tetracyanobutadienes (TCBDs) were obtained in good to excellent yields through a [2+2]-cycloaddition/[2+2]-retro-electrocyclization sequence. The influence of diverse functional groups on the yield of the reaction was investigated, in particular concerning multiple ynamides. These TCBDs were characterized by various spectroscopic techniques and electrochemistry and X-ray diffraction in some cases.
Type de document :
Article dans une revue
Chemistry - An Asian Journal, Wiley-VCH Verlag, 2017, 12 (12), pp.1338-1346. 〈10.1002/asia.201700353〉
Liste complète des métadonnées

Littérature citée [17 références]  Voir  Masquer  Télécharger

https://hal-univ-rennes1.archives-ouvertes.fr/hal-01544243
Contributeur : Laurent Jonchère <>
Soumis le : mercredi 5 juillet 2017 - 16:26:58
Dernière modification le : samedi 22 décembre 2018 - 19:33:31
Document(s) archivé(s) le : mardi 23 janvier 2018 - 21:58:03

Identifiants

Citation

Marie Betou, Raphael J. Durand, Antoine Sallustrau, Claire Gousset, Erwann Le Coz, et al.. Reactivity of Functionalized Ynamides with Tetracyanoethylene: Scope, Limitations and Optoelectronic Properties of the Adducts. Chemistry - An Asian Journal, Wiley-VCH Verlag, 2017, 12 (12), pp.1338-1346. 〈10.1002/asia.201700353〉. 〈hal-01544243〉

Partager

Métriques

Consultations de la notice

256

Téléchargements de fichiers

26