N. Lewis and D. Nocera, Powering the planet: Chemical challenges in solar energy utilization, Proceedings of the National Academy of Sciences, vol.312, issue.5771, pp.15729-15735, 2006.
DOI : 10.1126/science.1123787

K. Ariga, J. Hill, and J. Q. , Layer-by-layer assembly as a versatile bottom-up nanofabrication technique for exploratory research and realistic application, Physical Chemistry Chemical Physics, vol.128, issue.200, pp.2319-2340, 2007.
DOI : 10.1295/koron.57.251

Y. Lu and W. Chen, Sub-nanometre sized metal clusters: from synthetic challenges to the unique property discoveries, Chemical Society Reviews, vol.124, issue.9, pp.3594-3623, 2012.
DOI : 10.1021/ja025897+

B. Ghosh and N. Shirahata, Colloidal silicon quantum dots: synthesis and luminescence tuning from the near-UV to the near-IR range, Science and Technology of Advanced Materials, vol.226, issue.1, pp.14207-14214, 2014.
DOI : 10.1021/nn4000644

H. Sun and Y. Sakka, Luminescent metal nanoclusters: controlled synthesis and functional applications, Science and Technology of Advanced Materials, vol.20, issue.1, pp.14205-014213, 2014.
DOI : 10.1039/c1cc14872a

S. Cordier, F. Grasset, and Y. Molard, Inorganic Molybdenum Octahedral Nanosized Cluster Units, Versatile Functional Building Block for Nanoarchitectonics, Journal of Inorganic and Organometallic Polymers and Materials, vol.450, issue.6, pp.189-204, 2015.
DOI : 10.1016/j.apcata.2012.09.053

URL : https://hal.archives-ouvertes.fr/hal-01082719

A. Perrin and C. Perrin, The molybdenum and rhenium octahedral cluster chalcohalides in solid state
URL : https://hal.archives-ouvertes.fr/hal-01070078

P. Gougeon, P. Gall, and R. Orabi, Chemistry of Materials, vol.24, issue.15, pp.2899-2908, 2012.
DOI : 10.1021/cm3009557

S. Fujii, T. Horiguchi, and S. Akagi, Quasi-One-Step Six-Electron Electrochemical Reduction of an Octahedral Hexanuclear Molybdenum(II) Cluster, Inorganic Chemistry, vol.55, issue.20, pp.10259-10266, 2016.
DOI : 10.1021/acs.inorgchem.6b01525

M. Potel, C. Perrin, and A. Perrin, New families of ternary molybdenum (II) chlorides with octahedral Mo6 clusters, Materials Research Bulletin, vol.21, issue.10, pp.1239-1245, 1986.
DOI : 10.1016/0025-5408(86)90053-X

N. Saito, Y. Wada, and P. Lemoine, Theoretical and experimental determination of the crystal structures of cesium???molybdenum chloride, Japanese Journal of Applied Physics, vol.55, issue.7, p.75502, 2016.
DOI : 10.7567/JJAP.55.075502

URL : https://hal.archives-ouvertes.fr/hal-01357414

K. Costuas, A. Garreau, and A. Bulou, Combined theoretical and time-resolved photoluminescence investigations of
URL : https://hal.archives-ouvertes.fr/hal-01222623

, Br a 6 ] 2? metal cluster units: evidence of dual emission, Phys Chem Chem Phys, vol.17, pp.28574-28585, 2015.

K. Kirakci, P. Kubát, and J. Langmaier, A comparative study of the redox and excited state properties of (nBu4N)2[Mo6X14] and (nBu4N)2[Mo6X8(CF3COO)6] (X = Cl, Br, or I), Dalton Transactions, vol.248, issue.19, pp.7224-7232, 2013.
DOI : 10.1016/j.ccr.2004.02.004

B. Dierre, X. Yuan, and T. Sekiguchi, Low-energy cathodoluminescence microscopy for the characterization of nanostructures, Science and Technology of Advanced Materials, vol.3, issue.4, p.43001, 2010.
DOI : 10.1007/s11664-010-1124-5

K. Kirakci, S. Cordier, and C. Perrin, Synthesis and characterization of Cs 2 Mo 6 X 14 (X = Br or I) hexamolybdenum cluster halides: efficient Mo6 cluster precursors for solution chemistry syntheses, Z Anorg Allg Chem, vol.631, pp.2-3411, 2005.
DOI : 10.1002/zaac.200400281

H. Schäfer, H. Schnering, and J. Tillack, Neue Untersuchungen über die Chloride des Molybdäns, Z Anorg Allg Chem, vol.353, pp.5-6281, 1967.

J. Sheldon, Polynuclear Complexes of Molybdenum(II), Nature, vol.31, issue.4694, pp.1210-1213, 1959.
DOI : 10.1038/1841210a0

J. Sheldon, Chloromolybdenum(II) compounds, J Chem Soc, pp.1007-1014, 1960.
DOI : 10.1039/jr9600001007

F. Cotton and N. Curtis, , Ion, Inorganic Chemistry, vol.4, issue.2, pp.241-244, 1965.
DOI : 10.1021/ic50024a025

M. Sokolov, M. Mikhailov, and E. Peresypkina, Highly luminescent complexes [Mo6X8(n-C3F7COO)6]2??? (X = Br, I), Dalton Transactions, vol.7, issue.24, pp.6375-6377, 2011.
DOI : 10.1021/ic050855i

K. Kirakci, P. Kubát, and M. Du?ek, A Highly Luminescent Hexanuclear Molybdenum Cluster - A Promising Candidate toward Photoactive Materials, European Journal of Inorganic Chemistry, vol.6, issue.19, pp.3107-3111, 2012.
DOI : 10.1039/b312398g

M. Sokolov, M. Mikhailov, and K. Brylev, } Clusters, Inorganic Chemistry, vol.52, issue.21, pp.12477-12481, 2013.
DOI : 10.1021/ic401377g

O. Efremova, M. Shestopalov, and N. Chirtsova, A highly emissive inorganic hexamolybdenum cluster complex as a handy precursor for the preparation of new luminescent materials, Dalton Trans., vol.46, issue.16, pp.6021-6025, 2014.
DOI : 10.1107/S0108767389011189

K. Kirakci, K. Fejfarová, and M. Kueráková, Hexamolybdenum Cluster Complexes with Pyrene and Anthracene Carboxylates: Ultrabright Red Emitters with the Antenna Effect, European Journal of Inorganic Chemistry, vol.36, issue.14, pp.2331-2336, 2014.
DOI : 10.1107/S0021889803012585

, chemistry: from condensed to discrete cluster units, C R Chim, vol.15, issue.9, pp.815-836, 2012.

V. Fedorov, Metal Clusters. As They Were Born in Siberia, Journal of Cluster Science, vol.44, issue.1, pp.3-15, 2015.
DOI : 10.1016/B978-0-08-097774-4.00212-6

P. Kuttipillai, Y. Zhao, and C. Traverse, Phosphorescent Nanocluster Light-Emitting Diodes, Advanced Materials, vol.98, issue.2, pp.320-326, 2016.
DOI : 10.1021/j100096a001

Y. Molard, Clustomesogens: Liquid Crystalline Hybrid Nanomaterials Containing Functional Metal Nanoclusters, Accounts of Chemical Research, vol.49, issue.8, pp.1514-1523, 2016.
DOI : 10.1021/acs.accounts.6b00236

URL : https://hal.archives-ouvertes.fr/hal-01364220

R. Lunt, P. Kuttipillai, and . Inventor, Nanocluster based light emitting device. United States patent US 2015/0069366 A1, 2015.

Y. Zhao and R. Lunt, Transparent Luminescent Solar Concentrators for Large-Area Solar Windows Enabled by Massive Stokes-Shift Nanocluster Phosphors, Advanced Energy Materials, vol.16, issue.9, pp.1143-1148, 2013.
DOI : 10.1002/adfm.200600489

Y. Zhao, G. Meek, and B. Levine, Near-Infrared Harvesting Transparent Luminescent Solar Concentrators, Advanced Optical Materials, vol.90, issue.7, pp.606-611, 2014.
DOI : 10.1063/1.456153

A. Renaud, F. Grasset, and B. Dierre, Inorganic Molybdenum Clusters as Light-Harvester in All Inorganic Solar Cells: A Proof of Concept, ChemistrySelect, vol.14, issue.10, pp.2284-2289, 2016.
DOI : 10.1002/ejic.201402076

URL : https://hal.archives-ouvertes.fr/hal-01475823

T. Aubert, F. Cabello-hurtado, and M. Esnault, Nanoparticles: Physico-Structural Characterizations and Toxicity Studies, The Journal of Physical Chemistry C, vol.117, issue.39, pp.20154-20163, 2013.
DOI : 10.1021/jp405836q

URL : https://hal.archives-ouvertes.fr/hal-01089447

K. Kirakci, P. Kubát, and K. Fejfarová, X-ray Inducible Luminescence and Singlet Oxygen Sensitization by an Octahedral Molybdenum Cluster Compound: A New Class of Nanoscintillators, Inorganic Chemistry, vol.55, issue.2, pp.803-809, 2016.
DOI : 10.1021/acs.inorgchem.5b02282

A. Solovieva, Y. Vorotnikov, and K. Trifonova, metal clusters, Journal of Materials Chemistry B, vol.5, issue.28, pp.4839-4846, 2016.
DOI : 10.1038/nprot.2010.2

C. Neaime, M. Amela-cortes, and F. Grasset, metal atom clusters, Physical Chemistry Chemical Physics, vol.71, issue.220, pp.30166-30173, 2016.
DOI : 10.1002/cyto.a.20449

URL : https://hal.archives-ouvertes.fr/hal-01089443

A. Beltrán, M. Mikhailov, and M. Sokolov, A photobleaching resistant polymer supported hexanuclear molybdenum iodide cluster for photocatalytic oxygenations and photodynamic inactivation of Staphylococcus aureus, Journal of Materials Chemistry B, vol.5, issue.36, pp.5975-5979, 2016.
DOI : 10.1002/asia.201000284

T. Truong, B. Dierre, and F. Grasset, Visible tunable lighting system based on polymer composites embedding ZnO and metallic clusters: from colloids to thin films, Science and Technology of Advanced Materials, vol.17, issue.1, pp.443-453, 2016.
DOI : 10.1364/JOSAA.10.002491

URL : https://hal.archives-ouvertes.fr/hal-01364251

T. Nguyen, F. Grasset, and B. Dierre, Fabrication of Transparent Thin Film of Octahedral Molybdenum Metal Clusters by Electrophoretic Deposition, ECS Journal of Solid State Science and Technology, vol.44, issue.10, pp.178-186, 2016.
DOI : 10.1016/j.cplett.2013.02.071

URL : https://hal.archives-ouvertes.fr/hal-01398036

R. Chevrel, M. Sergent, and J. Prigent, Sur de nouvelles phases sulfur??es ternaires du molybd??ne, Journal of Solid State Chemistry, vol.3, issue.4, pp.515-519, 1971.
DOI : 10.1016/0022-4596(71)90095-8

D. Aurbach, Z. Lu, and A. Schechter, Prototype systems for rechargeable magnesium batteries, Nature, vol.27, issue.82, pp.724-727, 2000.
DOI : 10.1016/0025-5408(92)90229-S

D. Aurbach, S. Suresh, and E. Levi, Progress in Rechargeable Magnesium Battery Technology, Advanced Materials, vol.32, issue.23, pp.4260-4267, 2007.
DOI : 10.1002/adma.200701495

I. Cl and . Br, Chem Phys Lett, vol.460, pp.4-6438, 2008.

R. Ramirez-tagle and R. Arratia-pérez, The luminescent [Mo 6 X 8 (NCS) 6 ] 2? (X = Cl, Br, I) clusters: a computational study based on time-dependent density functional theory including spin?orbit and solvent-polarity effects, Chem Phys Lett, vol.455, pp.1-338, 2008.

O. Efremova, Y. Vorotniknov, and K. Brylev, Octahedral molybdenum cluster complexes with aromatic sulfonate ligands, Dalton Transactions, vol.455, issue.124, pp.15427-15435, 2016.
DOI : 10.1016/j.cplett.2008.02.037

E. Mendili, Y. Bardeau, J. Randrianantoandro, and N. , Structural behavior of laser-irradiated ?-Fe 2 O 3 nanocrystals dispersed in porous silica matrix: ?-Fe 2 O 3 to ?-Fe 2 O 3 phase transition and formation of
URL : https://hal.archives-ouvertes.fr/hal-02132527

, Sci Technol Adv Mater, vol.17, issue.1, pp.597-609, 2016.

R. Bertoni, M. Lorenc, and H. Cailleau, Elastically driven cooperative response of a molecular material impacted by a laser pulse, Nature Materials, vol.35, issue.6, pp.606-610, 2016.
DOI : 10.1103/PhysRevLett.103.027402

URL : https://hal.archives-ouvertes.fr/hal-01294246

F. Grasset, F. Dorson, and S. Cordier, Water-in-Oil Microemulsion Preparation and Characterization of Cs2[Mo6X14]@SiO2 Phosphor Nanoparticles Based on Transition Metal Clusters (X???=???Cl, Br, and I), Advanced Materials, vol.118, issue.1, pp.143-148, 2008.
DOI : 10.1002/adma.200701686

URL : https://hal.archives-ouvertes.fr/hal-00414417

R. Egerton, P. Li, and M. Malac, Radiation damage in the TEM and SEM, Micron, vol.35, issue.6, pp.399-409, 2004.
DOI : 10.1016/j.micron.2004.02.003

T. Nagatomi, H. Nakamura, and Y. Takai, Approach to Quantitative Evaluation of Electron-Induced Degradation of SiO2 Film Surface with Different Amounts of Carbon Contaminations, e-Journal of Surface Science and Nanotechnology, vol.9, pp.277-288, 2011.
DOI : 10.1380/ejssnt.2011.277

O. Efremova, K. Brylev, and Y. Vorotnikov, Photoluminescent materials based on PMMA and a highly-emissive octahedral molybdenum metal cluster complex, Journal of Materials Chemistry C, vol.4, issue.3, pp.497-503, 2016.
DOI : 10.1039/c3ra46809g

H. Uoyama, K. Goushi, and K. Shizu, Highly efficient organic light-emitting diodes from delayed fluorescence, Nature, vol.50, issue.7428, pp.234-238, 2012.
DOI : 10.3987/COM-10-S(E)69

K. Kirakci, P. Kubát, and M. Kueráková, Water-soluble octahedral molybdenum cluster compounds Na2[Mo6I8(N3)6] and Na2[Mo6I8(NCS)6]: Syntheses, luminescence, and in vitro studies, Inorganica Chimica Acta, vol.441, pp.42-49, 2016.
DOI : 10.1016/j.ica.2015.10.043

M. Mikhailov, K. Brylev, and A. Virovets, } with nitrophenolates: synthesis and luminescence, New Journal of Chemistry, vol.53, issue.2, pp.1162-1168, 2016.
DOI : 10.1002/anie.201306438

M. Mikhailov, K. Brylev, and P. Abramov, Core Cluster Complexes by Terminal Carboxylate Ligands, Inorganic Chemistry, vol.55, issue.17, pp.8437-8445, 2016.
DOI : 10.1021/acs.inorgchem.6b01042

Y. Vorotnikov, M. Mikhailov, and K. Brylev, Synthesis, crystal structure, and luminescence properties of complexes (4-ViBnNMe3)2[{M6(??3-I)8}I6] (M = Mo, W; (4-ViBnNMe3)+ is trimethyl(4-vinylbenzyl)ammonium), Russian Chemical Bulletin, vol.25, issue.2-4, pp.2591-2596, 2015.
DOI : 10.1021/ic00233a019

A. Maverick, J. Najdzionek, and D. Mackenzie, Spectroscopic, electrochemical, and photochemical properties of molybdenum(II) and tungsten(II) halide clusters, Journal of the American Chemical Society, vol.105, issue.7, pp.1979-1882, 1983.
DOI : 10.1021/ja00345a034

M. Amela-cortes, Y. Molard, and S. Paofai, octahedral nano-building blocks, Dalton Transactions, vol.2, issue.1, pp.237-245, 2016.
DOI : 10.1039/C4TC02098G

URL : https://hal.archives-ouvertes.fr/hal-01236442

C. Katan, L. Pedesseau, and M. Kepenekian, Interplay of spin???orbit coupling and lattice distortion in metal substituted 3D tri-chloride hybrid perovskites, Journal of Materials Chemistry A, vol.77, issue.17, pp.9232-9240, 2015.
DOI : 10.1103/PhysRevB.77.045129

URL : https://hal.archives-ouvertes.fr/hal-01403303

A. Slavney, R. Smaha, and I. Smith, Chemical Approaches to Addressing the Instability and Toxicity of Lead???Halide Perovskite Absorbers, Inorganic Chemistry, vol.56, issue.1, pp.46-55, 2017.
DOI : 10.1021/acs.inorgchem.6b01336

R. Ramirez-tagle and R. Arratia-pérez, Electronic structure and molecular properties of the