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Journal articles
Structural analysis of a dimeric trinuclear zinc(II) complex based on a preorganized yet flexible strap porphyrin
Abstract : We report the solid-state structure of an unexpected trinuclear zinc dimeric porphyrin complex resulting of zinc insertion into a single strap porphyrin. The latter bears an overhanging carboxylic acid which usually interacts with metal cations either in out-of-plane (OOP) or in hanging-atop (HAT) coordination mode by changing its location above the porphyrin coordination site. However, in the present studies, the overhanging carboxylic group acts as a bidentate ligand and binds the OOP-bound zinc cation together with another zinc cation bridging two porphyrin units.
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01578531
Contributor : Laurent Jonchère Connect in order to contact the contributor
Submitted on : Tuesday, August 29, 2017 - 1:35:51 PM
Last modification on : Friday, January 7, 2022 - 3:50:02 AM
Contributor : Laurent Jonchère Connect in order to contact the contributor
Submitted on : Tuesday, August 29, 2017 - 1:35:51 PM
Last modification on : Friday, January 7, 2022 - 3:50:02 AM