H. Doucet, T. Ohkuma, K. Murata, T. Yokozawa, M. Kozawa et al., trans-[RuCl2(phosphan)2(1,2-diamin)]- und chiraletrans-[RuCl2(diphosphan)(1,2-diamin)]- Komplexe: lagerstabile Katalysatorvorstufen f??r die schnelle, produktive und stereoselektive Hydrierung von Ketonen, Angewandte Chemie, vol.122, issue.12, pp.1792-1796, 1998.
DOI : 10.1016/S0022-328X(00)92750-5

T. Ohkuma, M. Koizumi, K. Muçiz, G. Hilt, C. Kabuto et al., )(binap)(1,2-diamine):?? A Catalyst for Asymmetric Hydrogenation of Simple Ketones under Base-Free Conditions, Journal of the American Chemical Society, vol.124, issue.23, pp.6508-6509, 2002.
DOI : 10.1021/ja026136+

M. Vaquero, A. Suarez, S. Vargas, G. Bottari, E. Alvarez et al., Highly Enantioselective Imine Hydrogenation Catalyzed by Ruthenium Phosphane-Phosphite Diamine Complexes, Chemistry - A European Journal, vol.44, issue.49, pp.15586-15591, 2012.
DOI : 10.1021/ic0489387

J. S. Samec, J. E. Backvall, P. G. Andersson, and P. Brandt, Mechanistic aspects of transition metal-catalyzed hydrogen transfer reactions, Chemical Society Reviews, vol.20, issue.3, pp.237-248, 2006.
DOI : 10.1002/recl.19370560206

S. M. Samec and J. E. Backvall, Ruthenium-Catalyzed Transfer Hydrogenation of Imines by Propan-2-ol in Benzene, Chemistry - A European Journal, vol.8, issue.13, pp.2955-2961, 2002.
DOI : 10.1002/1521-3765(20020703)8:13<2955::AID-CHEM2955>3.0.CO;2-Q

B. Zhao, Z. Han, and K. Ding, The N???H Functional Group in Organometallic Catalysis, Angewandte Chemie International Edition, vol.41, issue.18, pp.4744-4788, 2013.
DOI : 10.1021/ar700133y

S. Werkmeister, S. Fleischer, S. Zhou, K. Junge, and M. Beller, Development of New Hydrogenations of Imines and Benign Reductive Hydroaminations: Zinc Triflate as a Catalyst, ChemSusChem, vol.131, issue.183, pp.777-782, 2012.
DOI : 10.1021/ja903547q

V. R. Sumerin, K. Chernichenko, M. Nieger, M. Leskel, B. Rieger et al., Highly Active Metal-Free Catalysts for Hydrogenation of Unsaturated Nitrogen-Containing Compounds, Advanced Synthesis & Catalysis, vol.128, issue.11-12, pp.2093-2110, 2011.
DOI : 10.1021/ja057222n

A. M. Kluwer, R. J. Detz, Z. Abiri, A. M. Van-der-burg, and J. N. Reek, Evolutionary Catalyst Screening: Iridium-Catalyzed Imine Hydrogenation, Advanced Synthesis & Catalysis, vol.39, issue.1, pp.89-95, 2012.
DOI : 10.1002/ejic.201000213

G. Newkome, Pyridylphosphines, Chemical Reviews, vol.93, issue.6, pp.2067-2089, 1993.
DOI : 10.1021/cr00022a006

D. B. Garagorri, W. Lackner-warton, C. M. Standfest-hauser, K. Mereiter, and K. Kirchner, Synthesis and characterization of iron and ruthenium complexes bearing P???N ligands based on 8-hydroxyquinoline, Inorganica Chimica Acta, vol.363, issue.14, pp.3674-3679, 2010.
DOI : 10.1016/j.ica.2010.05.019

R. J. Lundgren, M. A. Rankin, R. Mcdonald, G. Schatte, and M. A. Stradiotto, A Formally Zwitterionic Ruthenium Catalyst Precursor for the Transfer Hydrogenation of Ketones that Does Not Feature an Ancillary Ligand N???H Functionality, Angewandte Chemie International Edition, vol.663, issue.25, pp.4732-4735, 2007.
DOI : 10.1002/anie.200700345

M. Mastalir, M. Glatz, N. Gorgas, B. Stoger, E. Pittenauer et al., PNP Pincer Complexes, Chemistry - A European Journal, vol.138, issue.35, pp.12316-12320, 2016.
DOI : 10.1021/jacs.6b03709

F. Foubelo, C. Nájera, and M. Yus, Catalytic asymmetric transfer hydrogenation of ketones: recent advances, Tetrahedron: Asymmetry, vol.26, issue.15-16, pp.769-790, 2015.
DOI : 10.1016/j.tetasy.2015.06.016

A. Mikhailine, M. I. Maishan, and R. H. Morris, Asymmetric Transfer Hydrogenation of Ketimines Using Well-Defined Iron(II)-Based Precatalysts Containing a PNNP Ligand, Organic Letters, vol.14, issue.17, pp.4638-4631, 2012.
DOI : 10.1021/ol302079q

C. Zúñiga, S. A. Moya, M. Fuentealba, B. Aranda, and P. Aguirre, Catalytic hydrogenation of N-benzylideneaniline using a new complex of ruthenium(II) derived from 2-ferrocenyl-1,8-naphthyridine, Inorganic Chemistry Communications, vol.14, issue.6, pp.964-967, 2011.
DOI : 10.1016/j.inoche.2011.03.043

S. A. Moya, J. C. Araya, J. Gajardo, V. Guerchais, L. Toupet et al., Synthesis and characterization of ruthenium (II) carbonyl complexes containing naphthyridine and acetylacetonate ligands and their catalytic activity in the hydrogen transfer reaction, Inorganic Chemistry Communications, vol.27, pp.108-110, 2013.
DOI : 10.1016/j.inoche.2012.09.028

URL : https://hal.archives-ouvertes.fr/hal-00806979

O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. Howard, and H. Puschmann, : a complete structure solution, refinement and analysis program, Journal of Applied Crystallography, vol.42, issue.2, pp.339-341, 2009.
DOI : 10.1107/S0021889808042726

M. Sheldrick, A short history of SHELX, Acta Crystallogr. Sect. A. Found. Crystallogr, vol.2017, issue.64, pp.112-122