Synthesis of metathesis catalysts with fluorinated unsymmetrical N,N’-diaryl imidazoline-based NHC ligands - Archive ouverte HAL Access content directly
Journal Articles Journal of Fluorine Chemistry Year : 2017

Synthesis of metathesis catalysts with fluorinated unsymmetrical N,N’-diaryl imidazoline-based NHC ligands

Abstract

New olefin metathesis catalysts bearing unsymmetrical fluorinated NHC ligands with hexafluoroisopropylmethoxy group in ortho-positions of N-aryl-substituent have been synthesized. The effects of mono-ortho-arylsubstitution and the replacement of para-methyl N-aryl group with more electron-donating methoxy group in unsymmetrical fluorinated NHC ligand on the activity of complexes have been evaluated.
Fichier principal
Vignette du fichier
Masoud et al. - Synthesis of Metathesis Catalysts with Fluorinated.pdf (957.92 Ko) Télécharger le fichier
Origin : Files produced by the author(s)
Loading...

Dates and versions

hal-01581217 , version 1 (04-09-2017)

Identifiers

Cite

S.M. Masoud, M.A. Topchiy, A.S. Peregudov, Thierry Roisnel, Pierre H. Dixneuf, et al.. Synthesis of metathesis catalysts with fluorinated unsymmetrical N,N’-diaryl imidazoline-based NHC ligands. Journal of Fluorine Chemistry, 2017, 200, pp.66-76. ⟨10.1016/j.jfluchem.2017.06.004⟩. ⟨hal-01581217⟩
49 View
123 Download

Altmetric

Share

Gmail Facebook Twitter LinkedIn More