Skip to Main content Skip to Navigation
Journal articles

Phosphine-pyridonate ligands containing octahedral ruthenium complexes: Access to esters and formic acid

Abstract : The preparation of three well-defined ruthenium complexes arising from phosphine-pyridon-e/-ate ligands is described. Solvent dependent Lewis acidic species formation was observed with these complexes. Selective formation of acetals or esters from primary alcohols was observed in the presence of these catalysts. Preliminary evaluation of these complexes in the base free hydrogenation of carbon dioxide is also reported. © The Royal Society of Chemistry 2017.
Document type :
Journal articles
Complete list of metadatas

https://hal-univ-rennes1.archives-ouvertes.fr/hal-01581224
Contributor : Laurent Jonchère <>
Submitted on : Friday, October 6, 2017 - 5:21:01 PM
Last modification on : Thursday, March 5, 2020 - 2:01:31 PM
Long-term archiving on: : Monday, January 8, 2018 - 3:29:40 PM

File

Sahoo-Phosphine-Pyridonate Lig...
Files produced by the author(s)

Identifiers

Citation

A.R. Sahoo, F. Jiang, Christian Bruneau, G.V.M. Sharma, S. Suresh, et al.. Phosphine-pyridonate ligands containing octahedral ruthenium complexes: Access to esters and formic acid. Catalysis Science & Technology, Royal Society of Chemistry, 2017, 7 (31), pp.3492--3498. ⟨10.1039/c7cy00932a⟩. ⟨hal-01581224⟩

Share

Metrics

Record views

217

Files downloads

251