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Journal articles
Ruthenium-Catalyzed Tandem Activation of C≡N and B−H Bonds under Dihydrogen: Synthesis of BN Heterocycles
Abstract : The incorporation of a nitrile function ortho to the B(sp2)HNiPr2 group to obtain cyano(aryl)boranes and subsequent ruthenium-catalyzed transformation of these cyano(aryl)boranes under a dihydrogen atmosphere (0.1 MPa) provided direct access to NH-containing 1H-2,1-benzazaboroles as BN analogues of indene under very mild conditions (i.e., room temperature). The BN heterocycle could be functionalized from the corresponding lithium amide either by N-elementation with various p-block (C, Si, P, B) electrophiles or by palladium-catalyzed N-arylation with aryl bromides thus to provide a new and powerful protocol for B−N bond decoration.
Cited literature [2 references]
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01596178
Contributor : Laurent Jonchère <>
Submitted on : Thursday, October 5, 2017 - 1:46:07 PM
Last modification on : Tuesday, January 12, 2021 - 4:46:50 PM
Long-term archiving on: : Monday, January 8, 2018 - 12:34:55 PM
Contributor : Laurent Jonchère <>
Submitted on : Thursday, October 5, 2017 - 1:46:07 PM
Last modification on : Tuesday, January 12, 2021 - 4:46:50 PM
Long-term archiving on: : Monday, January 8, 2018 - 12:34:55 PM
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