Emission properties of diazines chromophores: Structure-properties relationship

Abstract : This article presents the photophysical properties of a series of diazine chromophores. The influence of five parameters has been studied: the presence of a diazine/benzodiazine fragment, the nature of the diazine fragment (1,3-diazine/1,4-diazine), the presence or not of an vinyl linker between diazine ring and phenylene fragments of the π-conjugated bridge, the presence of a phenylene/biphenylene linker and the nature of electron donating group (dimethylamino/diphenylamino). Taguchi's design of experiment combined with analysis of variance methodologies have been employed to highlight the main structural parameters influencing the position of absorption and emission maxima of dichloromethane solution and the extend of emission solvatochromic range exhibited by this family of chromophores. © 2017 Elsevier B.V.
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Journal of Photochemistry and Photobiology A: Chemistry, 2017, 348, pp.281-286. 〈10.1016/j.jphotochem.2017.08.060〉
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01619414
Contributeur : Laurent Jonchère <>
Soumis le : jeudi 19 octobre 2017 - 13:39:50
Dernière modification le : jeudi 11 janvier 2018 - 06:24:35

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S. Achelle, F. Robin-Le Guen. Emission properties of diazines chromophores: Structure-properties relationship. Journal of Photochemistry and Photobiology A: Chemistry, 2017, 348, pp.281-286. 〈10.1016/j.jphotochem.2017.08.060〉. 〈hal-01619414〉

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