Nonconventional Three-Component Hierarchical Host-Guest Assembly Based on Mo-Blue Ring-Shaped Giant Anion, gamma-Cyclodextrin, and Dawson-type Polyoxometalate

Mhamad Aly Moussawi 1 Mohamed Haouas 1 Sébastien Floquet 1 William E. Shepard 2 Pavel A. Abramov 3 Maxim N. Sokolov 3 Vladimir P. Fedin 3 Stéphane Cordier 4 Anne Ponchel 5, 6 Eric Monflier 5, 6 Jérôme Marrot 1 Emmanuel Cadot 1
1 ILV - Institut Lavoisier de Versailles
2 ESRF - European Synchrotron Radiation Facility
3 NSU - Novosibirsk State University
4 ISCR - Institut des Sciences Chimiques de Rennes
5 UCCS Artois - Unité de Catalyse et de Chimie du Solide - Site Artois
6 UCCS - Unité de Catalyse et de Chimie du Solide - UMR 8181
Abstract : In this communication, we report on a noteworthy hybrid supramolecular assembly built from three functional components hierarchically organized through noncovalent interactions. The one-pot synthesis procedure leads to the formation of large Mo-blue ring-shaped anion {Mo-154}, which contains the supramolecular adduct based on the symmetric encapsulation of the Dawson-type [P2W18O62](6) anion by two gamma-cyclodextrin units. Such a nanoscopic onion-like structure, noted [P2W18O62]@2 gamma-CD@{Mo-154} has been characterized by single-crystal X-ray diffraction, thus demonstrating the capability of the giant inorganic torus to develop relevant supramolecular chemistry, probing the strong affinity of the inner and outer faces of the gamma-CD for the polyoxometalate surfaces. Furthermore, interactions and behavior in solution have been studied by multinuclear NMR spectroscopy, which supports specific interactions between gamma-CD and POM units. Finally, the formation of this three-component hybrid assembly from one-pot procedure, in water and using nearly stoichiometric conditions, is discussed in terms of the driving forces orchestrating this highly efficient multilevel recognition process.
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Mhamad Aly Moussawi, Mohamed Haouas, Sébastien Floquet, William E. Shepard, Pavel A. Abramov, et al.. Nonconventional Three-Component Hierarchical Host-Guest Assembly Based on Mo-Blue Ring-Shaped Giant Anion, gamma-Cyclodextrin, and Dawson-type Polyoxometalate. Journal of the American Chemical Society, American Chemical Society, 2017, 139 (41), pp.14376-14379. ⟨10.1021/jacs.7b08058⟩. ⟨hal-01631922⟩

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