R. Sessoli, D. Gatteschi, A. Caneschi, and M. Novak, Magnetic bistability in a metal-ion cluster, Nature, vol.365, issue.6442, pp.141-143, 1993.
DOI : 10.1038/365141a0

M. Urdampilleta, S. Klyatskaya, J. Cleuziou, M. Ruben, and W. , Supramolecular spin valves, Nature Materials, vol.42, issue.7, pp.502-508, 2011.
DOI : 10.1021/nl801869b
URL : https://hal.archives-ouvertes.fr/hal-00976036

M. N. Leuenberger and D. , Loss,;1; Quantum computing in molecular magnets, Nature, pp.410-789, 2001.

A. Cornia, M. Mannini, P. Sainctavit, and R. , Sessoli,;1; Chemical strategies and characterization tools for the organization of single molecule magnets on surfaces, Chem. Soc. Rev, pp.40-3076, 2011.

A. L. Barra, A. Caneschi, A. Cornia, F. Fabrizi-de-biani, D. Gatteschi et al., Single-Molecule Magnet Behavior of a Tetranuclear Iron(III) Complex. The Origin of Slow Magnetic Relaxation in Iron(III) Clusters, Journal of the American Chemical Society, vol.121, issue.22, pp.121-5302, 1999.
DOI : 10.1021/ja9818755

S. Accorsi, A. Barra, A. Caneschi, G. Chastanet, A. Cornia et al., = 5 Ground State, Journal of the American Chemical Society, vol.128, issue.14, pp.4742-4755, 2006.
DOI : 10.1021/ja0576381

A. Barra, F. Bianchi, A. Caneschi, A. Cornia, D. Gatteschi et al., Talarico,;1; New Single-Molecule Magnets by Site-Specific Substitution: Incorporation of " Alligator Clips " into Fe4 Complexes, Eur. J. Inorg. Chem, pp.2007-4145, 2007.

M. Mannini, F. Pineider, P. Sainctavit, C. Danieli, E. Otero et al., Magnetic memory of a single-molecule quantum magnet wired to a gold surface, Nature Materials, vol.320, issue.3, pp.194-201, 2009.
DOI : 10.1038/nmat2374

M. Mannini, F. Pineider, C. Danieli, F. Totti, L. Sorace et al., Quantum tunnelling of the magnetization in a monolayer of oriented single-molecule magnets, Nature, vol.2, issue.7322, pp.468-417, 2010.
DOI : 10.1038/nature09478

V. Lanzilotto, L. Malavolti, S. Ninova, I. Cimatti, L. Poggini et al., Sessoli,;1; The Challenge of Thermal Deposition of Coordination Compounds: Insight into the Case of an Fe 4 Single Molecule Magnet, Chem. Mater, pp.28-7693, 2016.

N. Ishikawa, M. Sugita, and W. , Wernsdorfer,;1; Quantum tunneling of magnetization in lanthanide single-molecule magnets: bis(phthalocyaninato)terbium and bis(phthalocyaninato)dysprosium anions, Angew. Chem. Int. Ed. Engl, pp.44-2931, 2005.

L. Malavolti, M. Mannini, P. Car, G. Campo, F. Pineider et al., Erratic magnetic hysteresis of TbPc2 molecular nanomagnets, Journal of Materials Chemistry C, vol.24, issue.16, pp.2935-2942, 2013.
DOI : 10.1021/ic00214a016

L. Margheriti, D. Chiappe, M. Mannini, P. Car, P. Sainctavit et al., Xray detected magnetic hysteresis of thermally evaporated terbium double-decker oriented films, Adv. Mater, vol.1, issue.22, pp.5488-93, 2010.

F. Habib and M. , Lessons learned from dinuclear lanthanide nano-magnets, Chemical Society Reviews, vol.31, issue.8, pp.3278-3288, 2013.
DOI : 10.1039/B617898G

W. Zhu, S. Li, C. Gao, X. Xiong, Y. Zhang et al., Lanthanide dinuclear complexes constructed from mixed oxygen-donor ligands: the effect of substituent positions of the neutral ligand on the magnetic dynamics in Dy analogues, Dalton Transactions, vol.4, issue.11, pp.45-4614, 2016.
DOI : 10.1039/C4RA08729A

W. Zhang, Y. Tian, H. Li, P. Chen, W. Sun et al., ) complexes bridged by 2-methyl-8-hydroxylquinoline: replacement on the periphery coordinated ??-diketonate terminal leads to different single-molecule magnetic properties, Dalton Transactions, vol.6, issue.9, pp.45-3863, 2016.
DOI : 10.1039/C5SC01245G

J. Zhang, H. Zhang, Y. Chen, X. Zhang, Y. Li et al., Dong,;1; A series of dinuclear lanthanide complexes with slow magnetic relaxation for Dy2 and Ho2, Dalt. Trans, pp.45-16463, 2016.

W. Yu, F. Schramm, E. M. Pineda, Y. Lan, O. Fuhr et al., Single-molecule magnet behavior in 2,2???-bipyrimidine-bridged dilanthanide complexes, Beilstein Journal of Nanotechnology, vol.7, issue.7, pp.126-137, 2016.
DOI : 10.3762/bjnano.7.15

. Li, Reversible Luminescence Modulation upon an Electric Field on a Full Solid- State Device Based on Lanthanide Dimers, ACS Appl. Mater. Interfaces, vol.1, issue.8, pp.15551-15557, 2016.
URL : https://hal.archives-ouvertes.fr/hal-01338528

Y. Wang, C. Han, Y. Zhang, Q. Liu, C. Liu et al., Yin,;1; Fine-Tuning Ligand to Modulate the Magnetic Anisotropy in a Carboxylate-Bridged Dy2 Single- Molecule Magnet System, Inorg. Chem, pp.55-5578, 2016.

W. Wang, W. Qiao, H. Zhang, S. Wang, Y. Nie et al., Structures and magnetic properties of several phenoxo-O bridged dinuclear lanthanide complexes: Dy derivatives displaying substituent dependent magnetic relaxation behavior, Dalton Transactions, vol.14, issue.19, pp.45-8182, 2016.
DOI : 10.1002/chem.200701316

W. Sun, B. Yan, L. Jia, B. Wang, Q. Yang et al., Dinuclear dysprosium SMMs bridged by a neutral bipyrimidine ligand: two crystal systems that depend on different lattice solvents lead to a distinct slow relaxation behaviour, Dalton Transactions, vol.18, issue.21, pp.45-8790, 2016.
DOI : 10.1002/chem.201103816

I. Oyarzabal, B. Fernandez, J. Cepeda, S. Gomez-ruiz, A. J. Calahorro et al., Rodriguez-Dieguez,;1; Slow relaxation of magnetization in 3D-MOFs based on dysprosium dinuclear entities bridged by dicarboxylic linkers, CrystEngComm, pp.18-3055, 2016.

S. Benmansour, G. López-martínez, J. Canet-ferrer, and C. , Gómez-García,;1; A Family of Lanthanoid Dimers with Nitroanilato Bridges, Magnetochemistry, 2016.

X. Yi, G. Calvez, C. Daiguebonne, O. Guillou, and K. , Bernot,;1; Rational Organization of Lanthanide-Based SMM Dimers into Three-Dimensional Networks, Inorg. Chem, pp.54-5213, 2015.

W. Wang, H. Zhang, S. Wang, H. Shen, and H. Gao, Ligand Field Affected Single-Molecule Magnet Behavior of Lanthanide(III) Dinuclear Complexes with an 8-Hydroxyquinoline Schiff Base Derivative as Bridging Ligand, Inorganic Chemistry, vol.54, issue.22, pp.54-10610, 2015.
DOI : 10.1021/acs.inorgchem.5b01404

Y. Peng, V. Mereacre, A. Baniodeh, Y. Lan, M. Schlageter et al., Powell,;1; Effect of Ligand Field Tuning on the SMM Behavior for Three Related Alkoxide-Bridged Dysprosium Dimers, Inorg. Chem, pp.55-68, 2015.

S. Lin, J. Wu, C. Wang, L. Zhao, and J. , Tang,;1; Modulating Relaxation Dynamics of Dy2 Compounds through Carboxylate Coordination Modes, Eur. J. Inorg. Chem, pp.5488-5494, 2015.

K. Suzuki, R. Sato, and N. , Reversible switching of single-molecule magnet behaviors by transformation of dinuclear dysprosium cores in polyoxometalates, Chem. Sci., vol.41, issue.2, pp.596-600, 2013.
DOI : 10.1039/c2dt12235a

M. Ren, S. Bao, N. Hoshino, T. Akutagawa, B. Wang et al., Solvent Responsive Magnetic Dynamics of a Dinuclear Dysprosium Single-Molecule Magnet, Chemistry - A European Journal, vol.58, issue.29, pp.9619-9628, 2013.
DOI : 10.1016/j.crci.2008.08.005

F. Habib, G. Brunet, V. Vieru, I. Korobkov, L. F. Chibotaru et al., Murugesu,;1; Significant Enhancement of Energy Barriers in Dinuclear Dysprosium Single-Molecule Magnets Through Electron-Withdrawing Effects, J. Am. Chem. Soc, pp.135-13242, 2013.

F. Pointillart, Y. L. Gal, S. Golhen, O. Cador, and L. , Single-Molecule Magnet Behaviour in a Tetrathiafulvalene-Based Electroactive Antiferromagnetically Coupled Dinuclear Dysprosium(III) Complex, Chemistry - A European Journal, vol.32, issue.37, pp.17-10397, 2011.
DOI : 10.1107/S0021889898007717
URL : https://hal.archives-ouvertes.fr/hal-00875420

J. Long, F. Habib, P. Lin, I. Korobkov, G. Enright et al., Single-Molecule Magnet Behavior for an Antiferromagnetically Superexchange-Coupled Dinuclear Dysprosium(III) Complex, Journal of the American Chemical Society, vol.133, issue.14, pp.5319-5328, 2011.
DOI : 10.1021/ja109706y
URL : https://hal.archives-ouvertes.fr/hal-00597045

P. H. Lin, T. J. Burchell, R. Clerac, and M. , Dinuclear Dysprosium(III) Single-Molecule Magnets with a Large Anisotropic Barrier, Angewandte Chemie International Edition, vol.129, issue.46, pp.8848-8851, 2008.
DOI : 10.1007/978-3-642-70733-9
URL : https://hal.archives-ouvertes.fr/hal-00336318

X. Yi, K. Bernot, O. Cador, J. Luzon, G. Calvez et al., Influence of ferromagnetic connection of Ising-type DyIII-based single ion magnets on their magnetic slow relaxation, Dalton Transactions, vol.18, issue.19, pp.42-6728, 2013.
DOI : 10.1002/chem.201201167

C. Y. Chow, H. Bolvin, V. E. Campbell, R. Guillot, J. W. Kampf et al., derivative, Chemical Science, vol.135, issue.7, pp.4148-4159, 2015.
DOI : 10.1021/ja310642h
URL : https://hal.archives-ouvertes.fr/hal-01192827

D. Jiang, J. Collison, E. J. Van-slageren, and R. E. Mcinnes, Winpenny,;1; Direct measurement of dysprosium(III)dysprosium(III) interactions in a single-molecule magnet, Nat Commun, vol.5, 2014.

X. Yi, K. Bernot, F. Pointillart, G. Poneti, G. Calvez et al., A Luminescent and Sublimable DyIII-Based Single-Molecule Magnet, Chemistry - A European Journal, vol.29, issue.36, pp.11379-87, 2012.
DOI : 10.1107/S0021889895014920

E. Kiefl, M. Mannini, K. Bernot, X. Yi, A. Amato et al., Robust Magnetic Properties of a Sublimable Single-Molecule Magnet, ACS Nano, vol.10, issue.6, pp.10-5663, 2016.
DOI : 10.1021/acsnano.6b01817
URL : https://hal.archives-ouvertes.fr/hal-01338690

S. S. Nagarkar, B. Joarder, A. K. Chaudhari, S. Mukherjee, and S. K. , Ghosh,;1; Highly selective detection of nitro explosives by a luminescent metal-organic framework, Angew. Chemie -Int, pp.52-2881, 2013.

K. S. Asha, K. Bhattacharyya, and S. , Discriminative detection of nitro aromatic explosives by a luminescent metal???organic framework, J. Mater. Chem. C, vol.20, issue.47, pp.10073-10081, 2014.
DOI : 10.1088/0022-3727/39/16/008

S. Alvarez, P. Alemany, D. Casanova, J. Cirera, M. Llunell et al., Avnir,;1; Shape maps and polyhedral interconversion paths in transition metal chemistry, Coord. Chem. Rev, pp.249-1693, 2005.

D. Casanova, J. Cirera, M. Llunell, P. Alemany, D. Avnir et al., Alvarez,;1; Minimal Distortion Pathways in Polyhedral Rearrangements, J. Am. Chem. Soc, pp.126-1755, 2004.
DOI : 10.1021/ja036479n

A. P. Milanov, R. W. Seidel, D. Barreca, A. Gasparotto, M. Winter et al., Devi,;1; Malonate complexes of dysprosium: synthesis, characterization and application for LI-MOCVD of dysprosium containing thin films, pp.40-62, 2011.

K. Roodenko, M. Gensch, J. Rappich, K. Hinrichs, N. Esser et al., Time-Resolved Synchrotron XPS Monitoring of Irradiation-Induced Nitrobenzene Reduction for Chemical Lithography, The Journal of Physical Chemistry B, vol.111, issue.26, pp.7541-7550, 2007.
DOI : 10.1021/jp072440j

D. Popovici, G. Czeremuzkin, M. Meunier, and E. Sacher, Laser-induced metal-organic chemical vapor deposition (MOCVD) of Cu(hfac)(TMVS) on amorphous Teflon AF1600: an XPS study of the interface, Applied Surface Science, vol.126, issue.3-4, pp.198-204, 1998.
DOI : 10.1016/S0169-4332(98)00009-9

S. Bag, K. Roy, C. S. Gopinath, and C. R. , Hybrid Functional Material for the Electrocatalytic Reduction of Oxygen, ACS Applied Materials & Interfaces, vol.6, issue.4, pp.2692-2699, 2014.
DOI : 10.1021/am405213z

C. Gao, Q. Yang, B. Wang, Z. Wang, and S. Gao, Evaporable lanthanide single-ion magnet, CrystEngComm, vol.64, issue.22, pp.18-4165, 2016.
DOI : 10.1107/S0108767307043930

A. Lunghi, F. Totti, R. Sessoli, and S. , Sanvito,;1; The role of anharmonic phonons in underbarrier spin relaxation of Single Molecule Magnet, Nat. Commun, vol.10, 1038.

F. Habib, P. Lin, I. Korobkov, G. Enright, L. Ungur et al., Single-Molecule Magnet Behavior for an Antiferromagnetically Superexchange-Coupled Dinuclear Dysprosium ( III ) Complex, Chibotaru, M. Murugesu, vol.1, pp.5319-5328, 2011.
URL : https://hal.archives-ouvertes.fr/hal-00597045

R. A. Layfield, J. J. Mcdouall, S. A. Sulway, F. Tuna, D. Collison et al., Winpenny,;1; Influence of the N-Bridging Ligand on Magnetic Relaxation in an Organometallic Dysprosium Single-Molecule Magnet, Chem. A Eur, J, pp.16-4442, 2010.

K. Bernot, L. Bogani, A. Caneschi, D. Gatteschi, and R. , Sessoli,;1; A Family of Rare-Earth- Based Single Chain Magnets:Playing with Anisotropy, J. Am. Chem. Soc, pp.128-7947, 2006.

D. A. Shirley, High-Resolution X-Ray Photoemission Spectrum of the Valence Bands of Gold, Physical Review B, vol.26, issue.12, pp.4709-4714, 1972.
DOI : 10.1103/PhysRevLett.26.1108

B. O. Roos, P. R. Taylor, and P. E. , Sigebahn,;1; A complete active space SCF method (CASSCF) using a density matrix formulated super-CI approach, Chem. Phys, pp.48-157, 1980.

P. Å. Malmqvist, B. O. Roos, and B. , Schimmelpfennig,;1; The restricted active space (RAS) state interaction approach with spin?orbit coupling, Chem Phys. Lett, pp.357-230, 2002.

P. Malmqvist and B. , The CASSCF state interaction method, Chemical Physics Letters, vol.155, issue.2, pp.189-194, 1989.
DOI : 10.1016/0009-2614(89)85347-3

L. F. Chibotaru and L. , Ungur,;1; Ab initio calculation of anisotropic magnetic properties of complexes. I. Unique definition of pseudospin Hamiltonians and their derivation, J. Chem. Phys, vol.137, issue.64112, 2012.

L. F. Chibotaru, L. Ungur, and A. , The Origin of Nonmagnetic Kramers Doublets in the Ground State of Dysprosium Triangles: Evidence for a Toroidal Magnetic Moment, Angewandte Chemie International Edition, vol.55, issue.22, pp.4126-4129, 2008.
DOI : 10.1007/978-3-642-74599-7

F. Aquilante, P. Malmqvist, T. B. Pedersen, A. Ghosh, and B. , (diiminato)(NPh), Journal of Chemical Theory and Computation, vol.4, issue.5, pp.694-702, 2008.
DOI : 10.1021/ct700263h

O. Björn, P. Roos, A. V. Malmqvist, and P. Veryazov, Widmark,;1; Main Group Atoms and Dimers Studied with a New Relativistic ANO Basis Set, J. Phys. Chem. A, vol.108, pp.2851-2858, 2004.