From aqueous speciation to supramolecular assembly in alkaline earth-uranyl polyoxometalates

Abstract : The interplay between aqueous alkaline earth (Ca, Sr, Ba) polycationic speciation and uranyl-peroxide polyoxometalate selfassembly and evolution is described here using solution (Raman and X-ray scattering) and solid-state (microscopy, X-ray diffraction) characterization. Supramolecular assembly of Sr-encapsulated and decorated polyanions and polycations yields the fourth largest inorganic unit cell reported from single-crystal X-ray diffraction.
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Article dans une revue
Chemical Communications, Royal Society of Chemistry, 2017, 53 (69), pp.9550-9553. 〈10.1039/c7cc05357f〉
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01671249
Contributeur : Laurent Jonchère <>
Soumis le : vendredi 22 décembre 2017 - 10:14:36
Dernière modification le : vendredi 25 mai 2018 - 01:28:46

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Clement Falaise, Sarah M. Hickam, Peter C. Burns, May Nyman. From aqueous speciation to supramolecular assembly in alkaline earth-uranyl polyoxometalates. Chemical Communications, Royal Society of Chemistry, 2017, 53 (69), pp.9550-9553. 〈10.1039/c7cc05357f〉. 〈hal-01671249〉

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