Electronic Interplay between TTF and Extended-TCNQ Electrophores along a Ruthenium Bis(acetylide) Linker

Antoine Vacher 1 Morgan Aufftay 1 Frédéric Barrière 1 Thierry Roisnel 1 Dominique Lorcy 1
1 ISCR - Institut des Sciences Chimiques de Rennes
Abstract : A bis(TTF-butadiynyl) ruthenium D-D'-D complex, with intramolecular electronic interplay between the three electron-donating electrophores, was easily converted through a cycloaddition-retroelectrocyclization with TCNQ into a D-A-D'-A-D pentad complex, which exhibits an intense intramolecular charge transfer together with an electronic interplay between the two acceptors along the conjugated organometallic bridge.
Type de document :
Article dans une revue
Organic Letters, American Chemical Society, 2017, 19 (22), pp.6060-6063. 〈10.1021/acs.orglett.7b02818〉
Domaine :
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01671269
Contributeur : Laurent Jonchère <>
Soumis le : vendredi 22 décembre 2017 - 10:15:55
Dernière modification le : vendredi 16 novembre 2018 - 01:36:12

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Antoine Vacher, Morgan Aufftay, Frédéric Barrière, Thierry Roisnel, Dominique Lorcy. Electronic Interplay between TTF and Extended-TCNQ Electrophores along a Ruthenium Bis(acetylide) Linker. Organic Letters, American Chemical Society, 2017, 19 (22), pp.6060-6063. 〈10.1021/acs.orglett.7b02818〉. 〈hal-01671269〉

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