Electronic Interplay between TTF and Extended-TCNQ Electrophores along a Ruthenium Bis(acetylide) Linker

Antoine Vacher; Morgan Aufftay; Frédéric Barrière; Thierry Roisnel; Dominique Lorcy

doi:10.1021/acs.orglett.7b02818

Electronic Interplay between TTF and Extended-TCNQ Electrophores along a Ruthenium Bis(acetylide) Linker

Antoine Vacher ¹ Morgan Aufftay ¹ Frédéric Barrière ¹ Thierry Roisnel ¹ Dominique Lorcy ¹

1 ISCR - Institut des Sciences Chimiques de Rennes

Abstract : A bis(TTF-butadiynyl) ruthenium D-D'-D complex, with intramolecular electronic interplay between the three electron-donating electrophores, was easily converted through a cycloaddition-retroelectrocyclization with TCNQ into a D-A-D'-A-D pentad complex, which exhibits an intense intramolecular charge transfer together with an electronic interplay between the two acceptors along the conjugated organometallic bridge.

Type de document :

Article dans une revue

Organic Letters, American Chemical Society, 2017, 19 (22), pp.6060-6063. 〈10.1021/acs.orglett.7b02818〉

Domaine :

Chimie

Liste complète des métadonnées

https://hal-univ-rennes1.archives-ouvertes.fr/hal-01671269
Contributeur : Laurent Jonchère <>
Soumis le : vendredi 22 décembre 2017 - 10:15:55
Dernière modification le : samedi 22 décembre 2018 - 19:34:08

Electronic Interplay between TTF and Extended-TCNQ Electrophores along a Ruthenium Bis(acetylide) Linker

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Electronic Interplay between TTF and Extended-TCNQ Electrophores along a Ruthenium Bis(acetylide) Linker

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