Electronic Interplay between TTF and Extended-TCNQ Electrophores along a Ruthenium Bis(acetylide) Linker - Archive ouverte HAL Access content directly
Journal Articles Organic Letters Year : 2017

Electronic Interplay between TTF and Extended-TCNQ Electrophores along a Ruthenium Bis(acetylide) Linker

Abstract

A bis(TTF-butadiynyl) ruthenium D-D'-D complex, with intramolecular electronic interplay between the three electron-donating electrophores, was easily converted through a cycloaddition-retroelectrocyclization with TCNQ into a D-A-D'-A-D pentad complex, which exhibits an intense intramolecular charge transfer together with an electronic interplay between the two acceptors along the conjugated organometallic bridge.
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Dates and versions

hal-01671269 , version 1 (22-12-2017)

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Antoine Vacher, Morgan Aufftay, F Barriere, Thierry Roisnel, Dominique Lorcy. Electronic Interplay between TTF and Extended-TCNQ Electrophores along a Ruthenium Bis(acetylide) Linker. Organic Letters, 2017, 19 (22), pp.6060-6063. ⟨10.1021/acs.orglett.7b02818⟩. ⟨hal-01671269⟩
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