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Electronic Interplay between TTF and Extended-TCNQ Electrophores along a Ruthenium Bis(acetylide) Linker

Abstract : A bis(TTF-butadiynyl) ruthenium D-D'-D complex, with intramolecular electronic interplay between the three electron-donating electrophores, was easily converted through a cycloaddition-retroelectrocyclization with TCNQ into a D-A-D'-A-D pentad complex, which exhibits an intense intramolecular charge transfer together with an electronic interplay between the two acceptors along the conjugated organometallic bridge.
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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01671269
Contributor : Laurent Jonchère <>
Submitted on : Friday, December 22, 2017 - 10:15:55 AM
Last modification on : Friday, July 10, 2020 - 4:24:31 PM

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Antoine Vacher, Morgan Aufftay, Frédéric Barrière, Thierry Roisnel, Dominique Lorcy. Electronic Interplay between TTF and Extended-TCNQ Electrophores along a Ruthenium Bis(acetylide) Linker. Organic Letters, American Chemical Society, 2017, 19 (22), pp.6060-6063. ⟨10.1021/acs.orglett.7b02818⟩. ⟨hal-01671269⟩

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