Electronic Interplay between TTF and Extended-TCNQ Electrophores along a Ruthenium Bis(acetylide) Linker

Antoine Vacher; Morgan Aufftay; Frédéric Barrière; Thierry Roisnel; Dominique Lorcy

doi:10.1021/acs.orglett.7b02818

Journal articles

Electronic Interplay between TTF and Extended-TCNQ Electrophores along a Ruthenium Bis(acetylide) Linker

Antoine Vacher ¹ Morgan Aufftay ¹ Frédéric Barrière ¹ Thierry Roisnel ¹ Dominique Lorcy ^{1, *}

* Corresponding author

1 ISCR - Institut des Sciences Chimiques de Rennes

Abstract : A bis(TTF-butadiynyl) ruthenium D-D'-D complex, with intramolecular electronic interplay between the three electron-donating electrophores, was easily converted through a cycloaddition-retroelectrocyclization with TCNQ into a D-A-D'-A-D pentad complex, which exhibits an intense intramolecular charge transfer together with an electronic interplay between the two acceptors along the conjugated organometallic bridge.

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Journal articles

Domain :

Chemical Sciences

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https://hal-univ-rennes1.archives-ouvertes.fr/hal-01671269
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Submitted on : Friday, December 22, 2017 - 10:15:55 AM
Last modification on : Friday, July 2, 2021 - 2:45:02 PM

Electronic Interplay between TTF and Extended-TCNQ Electrophores along a Ruthenium Bis(acetylide) Linker

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Electronic Interplay between TTF and Extended-TCNQ Electrophores along a Ruthenium Bis(acetylide) Linker

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