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New chemistry of transition metal oxyhydrides

Abstract : In this review we describe recent advances in transition metal oxyhydride chemistry obtained by topochemical routes, such as low temperature reduction with metal hydrides, or high-pressure solid-state reactions. Besides the crystal chemistry, magnetic and transport properties of the bulk powder and epitaxial thin film samples, the remarkable lability of the hydride anion is particularly highlighted as a new strategy to discover unprecedented mixed anion materials.
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Y. Kobayashi, O. Hernandez, C. Tassel, H. Kageyama. New chemistry of transition metal oxyhydrides. Science and Technology of Advanced Materials, National Institute for Materials Science, 2017, 18 (1), pp.905-918. ⟨10.1080/14686996.2017.1394776⟩. ⟨hal-01671631⟩

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