Formation, Microstructure, and Conductivity of a Novel Ga2S3-Sb2S3-AgI Chalcogenide System

Xinyu Huang 1 Qing Jiao 1 Changgui Lin 1 Hongli Ma 2 Xianghua Zhang 2 Erwei Zhu 1 Xueyun Liu 1 Shixun Dai 1 Tiefeng Xu 1
1 NBUT - Ningbo University of Technology
2 ISCR - Institut des Sciences Chimiques de Rennes
Abstract : Novel glasses in a Ga2S3-Sb2S3-AgI system were prepared with a melt-quenching method, and their glass-forming region was identified. The maximum dissolvable AgI in glasses was 65 mol%. The thermal, optical, and structural properties of glasses were investigated as a function of AgI and Ga2S3 contents. The Ga2S3-Sb2S3-AgI glasses possess a wide region of transmission window (0.65-14 mu m). An ionic conductivity of approximately 1.01 x 10(-3) S/cm can be obtained for a 40 (0.8Sb(2)S(3)-0.2Ga(2)S(3))-60AgI glass at an ambient temperature, and the ionic conductivity increased as temperature increased. The relative activation energy of Ag+ conduction was also calculated. These novel glasses show potential for the combined application of infrared optics and solid electrolytes.
Document type :
Journal articles
Complete list of metadatas

Cited literature [35 references]  Display  Hide  Download
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01709532
Contributor : Laurent Jonchère <>
Submitted on : Wednesday, July 17, 2019 - 3:31:26 PM
Last modification on : Thursday, September 19, 2019 - 4:04:11 PM

File

s41598-018-20144-3.pdf
Publisher files allowed on an open archive

Identifiers

Collections

UNIV-RENNES | IVER | SCR_VC | UR1-UFR-SPM | ISCR | CNRS | INC-CNRS | INSA-GROUPE | UNIV-RENNES1

Citation

Xinyu Huang, Qing Jiao, Changgui Lin, Hongli Ma, Xianghua Zhang, et al.. Formation, Microstructure, and Conductivity of a Novel Ga2S3-Sb2S3-AgI Chalcogenide System. Scientific Reports, Nature Publishing Group, 2018, 8 (1), pp.1699. ⟨10.1038/s41598-018-20144-3⟩. ⟨hal-01709532⟩

Export

BibTeX TEI DC DCterms EndNote

Share

Metrics

Record views

126

Files downloads

61