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Journal articles
A Terminal Fluoride Ligand Generates Axial Magnetic Anisotropy in Dysprosium Complexes
Abstract : The first dysprosium complexes with a terminal fluoride ligand are obtained as air-stable compounds. The strong, highly electrostatic dysprosium-fluoride bond generates a large axial crystal-field splitting of the J=15/2 ground state, as evidenced by high-resolution luminescence spectroscopy and correlated with the single-molecule magnet behavior through experimental magnetic susceptibility data and ab initio calculations.
Cited literature [5 references]
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01717763
Contributor : Laurent Jonchère <>
Submitted on : Friday, May 4, 2018 - 4:06:34 PM
Last modification on : Friday, July 10, 2020 - 4:21:48 PM
Long-term archiving on: : Tuesday, September 25, 2018 - 4:20:26 AM
Contributor : Laurent Jonchère <>
Submitted on : Friday, May 4, 2018 - 4:06:34 PM
Last modification on : Friday, July 10, 2020 - 4:21:48 PM
Long-term archiving on: : Tuesday, September 25, 2018 - 4:20:26 AM
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A Terminal Fluoride Ligand Gen...
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