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A Terminal Fluoride Ligand Generates Axial Magnetic Anisotropy in Dysprosium Complexes

Abstract : The first dysprosium complexes with a terminal fluoride ligand are obtained as air-stable compounds. The strong, highly electrostatic dysprosium-fluoride bond generates a large axial crystal-field splitting of the J=15/2 ground state, as evidenced by high-resolution luminescence spectroscopy and correlated with the single-molecule magnet behavior through experimental magnetic susceptibility data and ab initio calculations.
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Submitted on : Friday, May 4, 2018 - 4:06:34 PM
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Lucie Norel, Lucy E. Darago, Boris Le Guennic, Khetpakorn Chakarawet, Miguel I. Gonzalez, et al.. A Terminal Fluoride Ligand Generates Axial Magnetic Anisotropy in Dysprosium Complexes. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2018, 57 (7), pp.1933-1938. ⟨10.1002/anie.201712139⟩. ⟨hal-01717763⟩

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