Hydrogenation of Carbonyl Derivatives Catalysed by Manganese Complexes Bearing Bidentate Pyridinyl-Phosphine Ligands - Archive ouverte HAL Access content directly
Journal Articles Advanced Synthesis and Catalysis Year : 2018

Hydrogenation of Carbonyl Derivatives Catalysed by Manganese Complexes Bearing Bidentate Pyridinyl-Phosphine Ligands

Abstract

Manganese(I) catalysts incorporating readily available bidentate 2-aminopyridinyl-phosphine ligands achieve a high efficiency in the hydrogenation of carbonyl compounds, significantly better than parent ones based on more elaborated and expensive tridentate 2,6-(diaminopyridinyl)-diphosphine ligands. The reaction proceeds with low catalyst loading (0.5 mol%) under mild conditions (50 degrees C) with yields up to 96%.
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hal-01737372 , version 1 (24-04-2018)

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Duo Wei, Antoine Bruneau-Voisine, Teo Chauvin, Vincent Dorcet, Thierry Roisnel, et al.. Hydrogenation of Carbonyl Derivatives Catalysed by Manganese Complexes Bearing Bidentate Pyridinyl-Phosphine Ligands. Advanced Synthesis and Catalysis, 2018, 360 (4), pp.676-681. ⟨10.1002/adsc.201701115⟩. ⟨hal-01737372⟩
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