J. =. Td, (s, 18H). 13 C NMR (126 MHz, CDCl3) ? (ppm): 163, dd, J = 5.9, 1.7 Hz, 2H), 7.25 (m, 2H), pp.153103-153109

4. Hz, 13 C NMR (126 MHz, CDCl3) ? (ppm): 163, Hz, 2H), 4.51 (d, J = 16.2 Hz, 2H), 4.13 (d, J = 16.3 Hz, 2H), 3.87 (d, J = 15.4 Hz CDCl3) ? (ppm): -144.41. HR-MS (FTMS + ): [M] + Calculated, pp.59-65

A. F. Henwood and E. Zysman-colman, ) complexes, Chem. Commun., vol.44, issue.5, pp.2017-807
DOI : 10.1039/C5DT02083B

K. P. Zanoni, R. L. Coppo, R. C. Amaral, and N. Y. Murakami-iha, ) complexes designed for light-emitting devices: beyond the luminescence color array, Dalton Transactions, vol.19, issue.33, pp.44-14559
DOI : 10.1002/adfm.200900911

S. Ladouceur and E. Zysman-colman, A Comprehensive Survey of Cationic Iridium(III) Complexes Bearing Nontraditional Ligand Chelation Motifs, Eur. J. Inorg. Chem, 2013.
DOI : 10.1002/ejic.201300476

R. Terki, L. Simoneau, and A. Rochefort, Tailoring the Photoluminescence Properties of Ionic Iridium Complexes, The Journal of Physical Chemistry A, vol.113, issue.3, p.534, 2009.
DOI : 10.1021/jp8086286

C. W. Lu, Y. Wang, and Y. Chi, Metal Complexes with Azolate-Functionalized Multidentate Ligands: Tactical Designs and Optoelectronic Applications, Chemistry - A European Journal, vol.54, issue.50, p.17892, 2016.
DOI : 10.1021/acs.inorgchem.5b00281

H. Li, P. Chou, Y. Hu, Y. Cheng, and R. Liu, Synthesis, Characterization, and Photophysical Properties of Iridium Complexes with an 8-Phenylquinoline Framework. The First Six-Membered Chelated Iridium Complexes for Electroluminance, Organometallics, vol.24, issue.6, p.1329, 2005.
DOI : 10.1021/om049192n

W. Wei and W. Huang, Color Tuning Based on a Six-membered Chelated Iridium(III) Complex with Aza-aromatic Ligand, Chem. Lett, vol.34, p.1668, 2005.

V. Thamilarasan, A. Jayamani, P. Manisankar, Y. Kim, and N. Sengottuvelan, Green-emitting phosphorescent iridium(III) complex: Structural, photophysical and electrochemical properties, Inorganica Chimica Acta, vol.408, p.240, 2013.
DOI : 10.1016/j.ica.2013.08.005

M. H. Tsai and C. C. Wu, Phosphorescent iridium(III) complexes with nonconjugated cyclometalated ligands, Chem. Eur. J. P.-T, vol.14, issue.10, p.5423, 2008.

C. Chen, C. Chang, C. Wu, F. Zhang, D. Ma et al., Synthesis, characterization, and photophysical and electroluminescent properties of blue-emitting cationic iridium(III) complexes bearing nonconjugated ligands An Unprecedented Family of Luminescent Iridium(III) Complexes Bearing a Six-Membered Chelated Tridentate C^N^C Ligand C?H Activation of Phenyl Imines and 2- Phenylpyridines with The scope of ambiphilic acetateassisted cyclometallation with half-sandwich complexes of iridium, rhodium and ruthenium Enhanced Luminescent Iridium(III) Complexes Bearing Aryltriazole Cyclometallated Ligands Cationic iridium(iii) complexes bearing a bis(triazole) ancillary ligand Blue light emitting electrochemical cells incorporating triazole-based luminophores, Highly Efficient Blue-Emitting Iridium(III) Carbene Complexes and Phosphorescent OLEDs Strongly Blue Luminescent Cationic Iridium(III) Complexes with an Electron-Rich Ancillary, pp.4542-6596, 2008.

. Ligand, Evaluation of Their Optoelectronic and Electrochemiluminescence Properties, Eur. J. Inorg. Chem, p.5329, 2013.

J. Baranoff, E. Zysman-colman, E. Henwood, A. F. Evariste, S. Slawin et al., Fluorine-free blue-green emitters for light-emitting electrochemical cells Rigid biimidazole ancillary ligands as an avenue to bright deep blue cationic iridium(iii) complexes. Faraday Discuss, J. Mater. Chem. C 2014 Z C, vol.2, issue.17421, pp.5793-165, 2014.

E. Ortí, H. J. Bolink, I. D. Samuel, E. Zysman-colman, and I. D. Samuel, Green Phosphorescence and Electroluminescence of Sulfur Pentafluoride-Functionalized Cationic Iridium(III) Complexes, Inorg. Chem, vol.54, p.5907, 2015.

E. Zysman-colman, Solubilised bright blue-emitting iridium complexes for solution processed OLEDs, J. Mater. Chem, 2016.

E. Zysman-colman, A. K. Pal, D. B. Cordes, A. M. Slawin, C. Momblona et al., Simple design to achieve red-to-near-infrared emissive cationic Ir(iii) emitters and their use in light emitting electrochemical cells Benzo[h]quinolin-10-yl-N Iridium(III) Complexes (26) Henwood, A. F.; Zysman-Colman, E. In Iridium(III) in Optoelectronic and Photonics Applications Archetype Cationic Iridium Complexes and Their Use in Solid-State Light-Emitting Electrochemical Cells Chiral Iridium(III) Complexes in Light-Emitting Electrochemical Cells: Exploring the Impact of Stereochemistry on the Photophysical Properties and Device Performances Conversion constants for redox potentials measured versus different reference electrodes in acetonitrile solutions at 25°C Accelerated Luminophore Discovery through Combinatorial Synthesis, Electrochemical Considerations for Determining Absolute Frontier Orbital Energy Levels of Conjugated Polymers for Solar Cell Applications, pp.218-767, 1974.

N. Marquet, A. Spannenberg, S. Gladiali, and M. Beller, Synthesis, Characterisation and Application of Iridium(III) Photosensitisers for Catalytic Water Reduction, Chem. Eur. J, vol.17, p.6998, 2011.

A. Prescimone, E. Ortí, C. E. Housecroft, E. C. Constable, and H. J. Bolink, Highly Stable Red- Light-Emitting Electrochemical Cells (34) For examples see, Enhanced Luminescent Iridium(III) Complexes Bearing Aryltriazole Cyclometallated Ligands, pp.3237-11514, 2011.

K. Suzuki, A. Kobayashi, S. Kaneko, K. Takehira, T. Yoshihara et al., Reevaluation of absolute luminescence quantum yields of standard solutions using a spectrometer with an integrating sphere and a back-thinned CCD detector, Physical Chemistry Chemical Physics, vol.108, issue.42, p.9850, 2009.
DOI : 10.6028/jres.113.004