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Journal articles
Crystal structure, Raman scattering and magnetic properties of CuCr2− xZrxSe4 and CuCr2− xSnxSe4 selenospinels
Abstract : Selenospinels, CuCr2− xMxSe4 (M = Zr and Sn), were synthesized via conventional solid-state reactions. The crystal structure of CuCr1.5Sn0.5Se4, CuCr1.7Sn0.3Se4, CuCr1.5Zr0.5Se4, and CuCr1.8Zr0.2Se4 were determined using single-crystal X-ray diffraction. All the phases crystallized in a cubic spinel-type structure. The chemical compositions of the single-crystals were examined using energy-dispersive X-ray analysis (EDS). Powder X-ray diffraction patterns of CuCr1.3Sn0.7Se4 and CuCr1.7Sn0.3Se4 were consistent with phases belonging to the Fd3¯m Space group. An analysis of the vibrational properties on the single-crystals was performed using Raman scattering measurements. The magnetic properties showed a spin glass behavior with increasing Sn content and ferromagnetic order for CuCr1.7Sn0.3Se4. © 2018
Cited literature [34 references]
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01740161
Contributor : Laurent Jonchère <>
Submitted on : Thursday, September 6, 2018 - 11:34:31 AM
Last modification on : Friday, July 10, 2020 - 4:23:54 PM
Long-term archiving on: : Saturday, December 8, 2018 - 12:19:39 AM
Contributor : Laurent Jonchère <>
Submitted on : Thursday, September 6, 2018 - 11:34:31 AM
Last modification on : Friday, July 10, 2020 - 4:23:54 PM
Long-term archiving on: : Saturday, December 8, 2018 - 12:19:39 AM
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