A. Moscowitz, Theoretical Aspects of Optical Activity. Part Small Molecules. Adv. Chem, vol.1

. Phys, , pp.67-112, 1962.

M. Kwit, P. Skowronek, J. Gawronski, and J. Frelek,

, Applications in Stereochemical Analysis of Synthetic Compounds, Natural Products, and Biomolecules, Comprehensive Chiroptical Spectroscopy Berova, N.; Polavarapu, P. L, vol.2

K. Nakanishi, , pp.39-72

K. Mislow and J. Siegel, Stereoisomerism and local chirality, Journal of the American Chemical Society, vol.106, issue.11, pp.3319-3328, 1984.
DOI : 10.1021/ja00323a043

Y. She and C. Chen, Helicenes: Synthesis and Applications, Chem. Rev, vol.2012, issue.112, pp.1463-1535

C. Thilgen, I. Gosse, and F. Diederich, Chirality in Fullerene Chemistry. Top. Stereochem, vol.23, pp.1-124, 2003.

A. Ghosh, Electronic Structure of Corrole Derivatives: Insights from Molecular Structures, Spectroscopy, Electrochemistry, and Quantum Chemical Calculations, Chemical Reviews, vol.117, issue.4, pp.3798-3881, 2017.
DOI : 10.1021/acs.chemrev.6b00590

Z. Gross and N. Galili, N-Substituted Corroles: A Novel Class of Chiral Ligands, Angewandte Chemie International Edition, vol.38, issue.16
DOI : 10.1002/(SICI)1521-3773(19990816)38:16<2366::AID-ANIE2366>3.0.CO;2-W

. Int and . Ed, , pp.2366-2369, 1999.

I. H. Wasbotten, T. Wondimagegn, and A. Ghosh, -Triarylcorroles. Highly Substituent-Sensitive Soret Bands as a Distinctive Feature of High-Valent Transition Metal Corroles, Journal of the American Chemical Society, vol.124, issue.27, pp.8104-8116, 2002.
DOI : 10.1021/ja0113697

Z. Ou, J. Shao, H. Zhao, K. Ohkubo, I. H. Wasbotten et al.,

M. , Spectroelectrochemical and ESR Studies of Highly Substituted Copper Corroles, J

, Porphyrins Phthalocyanines, vol.8, pp.1236-1247, 2004.

M. Bröring, F. Bregier, E. C. Tejero, C. Hell, and M. C. Holthausen, Revisiting the Electronic Ground State of Copper Corroles, Angewandte Chemie International Edition, vol.54, issue.3, pp.445-448, 2007.
DOI : 10.1002/3527600043

K. E. Thomas, A. B. Alemayehu, J. Conradie, C. Beavers, and A. Ghosh, Synthesis and Molecular Structure of Gold Triarylcorroles, Inorganic Chemistry, vol.50, issue.24, pp.12844-12851, 2011.
DOI : 10.1021/ic202023r

S. Berg, K. E. Thomas, C. M. Beavers, A. Ghosh, and . Undecaphenylcorroles, Undecaphenylcorroles, Inorganic Chemistry, vol.51, issue.18, pp.9911-9916, 2012.
DOI : 10.1021/ic301388e

K. E. Thomas, C. M. Beavers, and A. Ghosh, Molecular Structure of a Gold

, Octakis(trifluoromethyl)-meso-triarylcorrole: An 85° Difference in Saddling Dihedral Relative to Copper, Mol. Phys, vol.2012, issue.110, pp.2439-2444

A. B. Alemayehu, L. K. Hansen, A. Ghosh, . Nonplanar, and . Noninnocent, Nonplanar, Noninnocent, and Chiral: A Strongly Saddled Metallocorrole, Inorganic Chemistry, vol.49, issue.17, pp.7608-7610, 2010.
DOI : 10.1021/ic1008736

K. E. Thomas, H. Vazquez-lima, Y. Fang, Y. Song, K. J. Gagnon et al., Ligand Noninnocence in Coinage Metal Corroles: A Silver Knife-Edge. Chem

. J. -eur, , pp.16839-16847, 2015.

K. E. Thomas, I. H. Wasbotten, and A. Ghosh, Copper ??-Octakis(trifluoromethyl)corroles: New Paradigms for Ligand Substituent Effects in Transition Metal Complexes, Inorganic Chemistry, vol.47, issue.22, pp.10469-10478, 2008.
DOI : 10.1021/ic801101k

K. E. Thomas, J. Conradie, L. K. Hansen, and A. Ghosh, A Metallocorrole with Orthogonal Pyrrole Rings, European Journal of Inorganic Chemistry, vol.22, issue.12, pp.1865-1870, 2011.
DOI : 10.1002/jcc.1056

C. Schies, A. B. Alemayehu, H. Vazquez-lima, and K. E. Thomas,

A. Ghosh, Metallocorroles as Inherently Chiral Chromophores: Resolution and Electronic Circular Dichroism Spectroscopy of a Tungsten Biscorrole, Chem. Commun, vol.53, pp.6121-6124, 2017.

A. B. Alemayehu, H. Vazquez-lima, L. J. Mccormick, and A. Ghosh, Relativistic effects in metallocorroles: comparison of molybdenum and tungsten biscorroles, Chemical Communications, vol.8, issue.43, pp.6914-6920, 2016.
DOI : 10.1021/ct300006h

A. B. Alemayehu, H. Vazquez-lima, K. J. Gagnon, and A. Ghosh, Tungsten Biscorroles: New Chiral Sandwich Compounds, Chemistry - A European Journal, vol.105, issue.20, pp.6914-6920, 2016.
DOI : 10.1063/1.472829

R. L. 21-halterman and S. T. Jan, Catalytic asymmetric epoxidation of unfunctionalized alkenes using the first D4-symmetric metallotetraphenylporphyrin, The Journal of Organic Chemistry, vol.56, issue.18, pp.5253-5254, 1991.
DOI : 10.1021/jo00018a008

R. L. 22-halterman and X. Mei, Synthesis of D2-symmetric 5,10,15,20-tetraarylporphyrins from C2-symmetric benzaldehydes and achiral aryldipyrromethanes, Tetrahedron Letters, vol.37, issue.35, pp.6291-6294, 1996.
DOI : 10.1016/0040-4039(96)01379-2

B. 23-koszarna and D. T. Gryko, O???MeOH Mixture, The Journal of Organic Chemistry, vol.71, issue.10, pp.3707-3717, 2006.
DOI : 10.1021/jo060007k

. Thomas,

R. L. Halterman, S. Jan, H. L. Nimmons, D. J. Standlee, and M. A. Khan, Synthesis and catalytic reactivity of D4-symmetric dinorbornabenzene-derived metallotetraarylporphyrins, Tetrahedron, vol.53, issue.33, pp.11257-11276, 1997.
DOI : 10.1016/S0040-4020(97)00729-1

J. Wang, Y. Zhang, Z. Xu, and V. Lo,

C. Carbene, Insertion Catalyzed by a Chiral Iridium(III) Complex of D 4 -Symmetric Porphyrin Ligand, ACS Catal, vol.2013, issue.3, pp.1144-1148

H. Thu, G. Tong, . S-m, J. Huang, S. Chan et al., Highly Selective Metal Catalysts for Intermolecular Carbenoid Insertion into Primary C???H Bonds and Enantioselective C???C Bond Formation, Angewandte Chemie International Edition, vol.36, issue.50, pp.9747-9751, 2008.
DOI : 10.1002/anie.200803157

I. 27-nicolas, S. Chevance, P. Le-maux, and G. Simonneaux, Chiral recognition of amines and amino acid derivatives by optically active ruthenium Halterman porphyrins in organic solvents and water, Tetrahedron: Asymmetry, vol.21, issue.13-14, pp.1788-1792, 2010.
DOI : 10.1016/j.tetasy.2010.05.026

R. L. 28-halterman, S. Jan, A. H. Abdulwali, and D. J. Standlee, Synthesis and catalytic reactivity of sterically and electronically modified D4-symmetric metallotetraarylporphyrins, Synthesis and Catalytic Reactivity of Sterically and Electronically Modified D 4 -Symmetric Metallotetraarylporphyrins, pp.11277-11296, 1997.
DOI : 10.1016/S0040-4020(97)00730-8

N. Amiri, P. Le-maux, H. Srour, and H. Nasri,

, Porphyrin: a New route for Fine-tuning Chiral Iron and Manganese Porphyrins with Application in Epoxidation and Hydroxylation reactions using Hydrogen Peroxide as Oxidant, Tetrahedron, vol.70, pp.8836-8842, 2014.

H. Srour, P. Le-maux, and G. Simmoneax, Enantioselective Manganese-Porphyrin-Catalyzed Epoxidation and C???H Hydroxylation with Hydrogen Peroxide in Water/Methanol Solutions, Inorganic Chemistry, vol.51, issue.10
DOI : 10.1021/ic300457z
URL : https://hal.archives-ouvertes.fr/hal-00870340

, Inorg. Chem, vol.2012, issue.51, pp.5850-5856

J. E. 31-jones, J. V. Ruppel, G. Gao, and T. M. Moore,

, Asymmetric Olefin Aziridination with Diphenylphosphoryl Azide, J. Org. Chem, vol.73, pp.7260-7265, 2008.

V. 32-subbarayan, J. V. Ruppel, S. Zhu, and J. A. Perman,

, Cobalt-Catalyzed Aziridination of Alkenes with Trichloroethoxysulfonyl Azide (TcesN 3 ) Chem

. Commun, , pp.4266-4268, 2009.

H. Jiang, K. Lang, H. Lu, L. Wojtas, and X. Zhang,

, Allyl Azidoformates via Cobalt(II)-Based Metalloradical Catalysis, J. Am. Chem. Soc, vol.2017, issue.139, pp.9164-9167

. Thomas,

T. Lai, F. Chan, P. So, D. Ma, K. Wong et al., Alkene cyclopropanation catalyzed by Halterman iron porphyrin: participation of organic bases as axial ligands, Dalton Transactions, vol.124, issue.40, pp.4845-4851, 2006.
DOI : 10.1039/b606757c

C. M. Che, J. S. Huang, F. W. Lee, Y. Li, T. S. Lai et al.,

W. C. Lo, S. M. Peng, and . Zhou, Z. Y. Asymmetric Inter-and Intramolecular Cyclopropanation

, Alkenes Catalyzed by Chiral Ruthenium Porphyrins. Synthesis and Crystal Structure of a Chiral Metalloporphyrin Carbene Complex, J. Am. Chem. Soc, vol.123, pp.4119-4129, 2001.

I. 36-nicolas, P. Le-maux, and G. Simonneaux, Synthesis of chiral water-soluble metalloporphyrins (Fe, Ru,): new catalysts for asymmetric carbene transfer in water, Tetrahedron Letters, vol.49, issue.40
DOI : 10.1016/j.tetlet.2008.07.133

, Tetrahedron Lett, vol.49, pp.5793-5795, 2008.

I. Nicolas, T. Roisnel, P. Le-maux, and G. Simonneaux, Asymmetric intermolecular cyclopropanation of alkenes by diazoketones catalyzed by Halterman iron porphyrins, Tetrahedron Letters, vol.50, issue.36
DOI : 10.1016/j.tetlet.2009.06.131

, Tetrahedron Lett, vol.50, pp.5149-5151, 2009.

.. Y. 38-chen, J. V. Ruppel, and X. P. Zhang, Cobalt-Catalyzed Asymmetric Cyclopropanation of Electron-Deficient Olefins, Journal of the American Chemical Society, vol.129, issue.40, pp.12074-12075, 2007.
DOI : 10.1021/ja074613o

E. Rose, B. Andrioletti, S. Zriga, and M. Quelquejeu-ethève, Enantioselective epoxidation of olefins with chiral metalloporphyrin catalysts, Chemical Society Reviews, vol.10, issue.7, pp.573-583, 2005.
DOI : 10.1021/cr020443g
URL : https://hal.archives-ouvertes.fr/hal-00017170

G. Simonneaux, P. Le-maux, S. Chevance, and H. Srour, Recent Advances in Catalysis by Water-Soluble Metalloporphyrins, In Handbook of Porphyrin Science. Kadish, K. M
DOI : 10.1142/9789814397605_0004
URL : https://hal.archives-ouvertes.fr/hal-00873109

M. Guilard and R. , , pp.377-410, 2012.

G. Simonneaux, H. Srour, P. Le-maux, S. Chevance, and D. Carrie, Metalloporphyrin Symmetry in Chiral Recognition and Enantioselective Catalysis, 42 Sheldrick, G. M. SHELXT -Integrated Space-Group and Crystal-Structure Determination, pp.210-221
DOI : 10.1002/anie.201205603
URL : https://hal.archives-ouvertes.fr/hal-01114611

, Acta Cryst. 2015, vol.71, pp.3-8

G. M. Sheldrick, Crystal Structure Refinement with SHELXL. Acta Cryst, pp.3-8, 2015.