J. Tang and P. Zhang, Lanthanide Single Molecule Magnets, 2015.
DOI : 10.1007/978-3-662-46999-6

M. Murugesu and P. Zhang, Lanthanides and Actinides in Molecular Magnetism, 2015.

C. Wang, S. Xue, S. Lin, J. Tang, Y. Meng et al., Equatorially Coord inated Lanthanide Single Ion Magnets Understanding the Magnetic Anisotropy toward Single-Ion Magnets, J. Am. Chem. Soc. Acc. Chem. Res. J Chem. ? Asian J, vol.136, issue.12, pp.4484-4487, 2014.

D. N. Woodruff, R. E. Winpenny, and R. A. Layfield, Lanthanide Single-Molecule Magnets, Chemical Reviews, vol.113, issue.7, pp.5110-5148, 2013.
DOI : 10.1021/cr400018q

D. E. Man, W. H. Harman, T. D. Harris, G. J. Long, C. J. Chang et al., Slow Magnetic Relaxat ion in a High-Spin Iron(II) Co mple x, J. Am. Chem. Soc, vol.132, issue.2, pp.1224-1225, 2010.

T. D. Harris, D. E. Freed-man, H. Fong, A. Chang, and . Rinehart, J. D

A. Ozarowski, M. T. Sougrati, F. Grandjean, G. J. Long, and . Long, J. R

C. J. Chang, Slow Magnetic Relaxat ion in a Family of Trigonal Pyramidal Iron(II) Pyrro lide Co mp lexes, J. Am. Chem. Soc, vol.132, pp.18115-18126, 2010.

P. E. Kazin, M. A. Zy-kin, L. A. Trusov, A. A. Eliseev, O. V. Magdysyuk et al., A Co-based single-molecule magnet confined in a bariu m phosphate apatite matrix with a high energy barrier for magnetization relaxat ion, Chem. Commun. J, vol.2017, issue.53, pp.5416-5419

I. Castro, P. Del-torro, M. Deniz, C. Ru-iz-perez, C. Yuste et al., Reversib le So lvatomagnetic Switching in a Single-Ion Magnet fro m an Entatic State, Chem. Sci. J. M.; Xiao, D. J.; Atanasov, M J, vol.2017, issue.83, pp.3694-3702

F. Neese, J. R. Long, N. Ishikawa, M. Sugita, T. Ishikawa et al., Magnetic Blocking in a Linear Iron(I) Co mp lex Lanthanide Double-Decker Co mp lexes Functioning as Magnets at the Single-Molecular Level, On Approaching the Limit of Molecular Magnetic Anisotropy: A Near- Perfect Pentagonal Bipyramidal Dysprosium(III) Single-Molecu le Magnet, pp.577-581, 2003.

B. Wang, H. Sun, Z. Wang, S. Gao, and K. Chakarawet, An Organometallic Single-Ion Magnet(III) Single-Molecule Magnet, J. Am. Chem. Soc. Angew. Chem. Int. Ed. B, vol.133, issue.54, pp.4730-4733, 2011.

M. I. Gon-zalez, J. H. Olshansky, S. Rigaut, J. R. Long, F. Guo et al., A Terminal Fluoride Ligand Generates A xial Magnetic Anisotropy in Dysprosium Complexes A Dysprosium Metallocene Single-Molecule Magnet Functioning at the A xial Limit Molecula r Magnetic Hysteresis at 60 Kelv in in Dysprosocenium, Sessoli, R. Quantum Tunneling of Magnetization and Related Phenomena in Molecular Materials, pp.11445-11449, 1933.

C. Martí-gastaldo, A. Gaita-ariño, S. Jiang, B. Wang, G. Su et al., A Mononuclear Dysprosium Co mplex Featuring Single-Molecule- Magnet Behavior Molecular (Nano) Magnets as Test Grounds of Quantum Mechanics Giant Hysteresis of Single-Molecu le Magnets Adsorbed on a Nonmagnetic Insulator Fine-tuning the Local Sy mmetry to Attain Record Blocking Temperature and Magnetic Remanence in a Single-Ion Magnet, Mononuclear Lanthanide Single- Molecule Magnets Based on Polyoxo metalates Structures and Magnetic Properties of Dysprosium Co mple xes: the Effect of Crystallization Temperature Murugesu, M. The Use of Magnetic Dilution To Elucidate the Slow Magnetic Relaxat ion Effects of a Dy 2 Single-Molecule Magnet. J. Am, pp.8874-8875, 2008.

. Chem, L. Soczhang, J. Jung, P. Zhang, M. Guo et al., Site-Resolved Two-Step Relaxation Process in an Asymmetric Dy 2 Single-Molecule Magnet, Chem. ? Eur. J. J, vol.133, issue.22, pp.8830-8833, 2011.

M. Boulon, G. Campo, F. Point-illart, C. L. Pereira, B. Le-guennic et al., Magnetic Poles Determinations and Robustness of Memory Effect upon Solubilization in a Dy III -Based Single Ion Magnet Antimony-ligated dysprosium single-molecu le magnets as catalysts for stibine dehydrocoupling Magnetic Memory in an Isotopically En riched and Magnetically Isolated Mononuclear Dysprosium Co mplex Optimization of Magnetic Relaxation and Isotopic Enrich ment in Dimeric Dy III Single-Molecule Magnets, Ouahab, L. Isotopically enriched poly morphs of dysprosium single mo lecule magnets, pp.16332-16335, 2015.

, Radical-Bridged Terbiu m Co mplex Exh ibiting Magnetic Hysteresis at 14

R. A. Layfield, J. Am. Chem. Soc, vol.133, pp.14236-14239, 2011.

J. J. Mcdouall, S. A. Su-lway, F. Tuna, D. Collison, and R. E. Winpenny, Influence of the N-Bridging Ligand on Magnetic Relaxation in an Organometallic Dysprosium Single-Mo lecule Magnet, Chem. ? Eur. J, vol.16, pp.4442-4446, 2010.

J. Wu, J. Jung, P. Zhang, H. Zhang, J. Tang et al., Cis???trans isomerism modulates the magnetic relaxation of dysprosium single-molecule magnets, Chemical Science, vol.54, issue.6, pp.3632-3639, 2016.
DOI : 10.1002/anie.201409887
URL : https://hal.archives-ouvertes.fr/hal-01341568

J. Liu, Y. Chen, and W. Lin,

W. Wernsdorfer, L. F. Ch-ibotaru, and M. Tong, Switching the anisotropy barrier of a single-ion magnet by symmetry change fro m quasi-D 5h to quasi-Oh, Chem. Sci, vol.4, pp.3310-3316, 2013.

K. Bernot, J. Lu-zon, L. Bogani, M. Etienne, C. Sangregorio et al., Magnetic Anisotropy of Dysprosium(III) in a Low-Symmetry Environment: A Theoretical and Experimental Investigation, Journal of the American Chemical Society, vol.131, issue.15, pp.5573-5579, 2009.
DOI : 10.1021/ja8100038
URL : https://hal.archives-ouvertes.fr/hal-00492555

. Chem, , pp.13770-13778, 2013.

S. Lin, S. Jiang, J. Tang, and B. Wang, Capping Ligand Perturbed Slo w Magnetic Relaxation in Dysprosium Single-Ion Magnets

, Chem. ? Eur. J, vol.17, pp.12476-12481, 2011.

G. Chen, Y. Guo, J. Tian, J. Tang, W. Gu et al., Enhancing Anisotropy Barriers of Dysprosium(III) Single-Ion Magnets, Chemistry - A European Journal, vol.46, issue.9, pp.2484-2487, 2012.
DOI : 10.1039/c0cc00966k

M. Guo, Y. Xu, J. Wu, L. Zhao, and J. Tang, single-molecule magnets, Dalton Transactions, vol.48, issue.290, pp.8252-8258
DOI : 10.1039/c2cc32518g

F. H. Case, E. Koft, and G. M. Sheldrick, The Synthesis of Certain Substituted 1,3,5- Triazines Containing the Ferroin Group SHELXS-97 Program for Crystal Structure Solution. University of Go ? ttingen: Germany: 1997; (b)Sheldrick, G. A short history of SHELX, J. Am. Chem. Soc. Acta Crystallogr. Sect. A Acta Crystallogr. Sect, vol.81, issue.71, pp.905-906, 1959.

G. A. Bain, J. F. Berry, J. Lu-zon, and R. Sessoli, Diamagnetic Corrections and Pascal's Constants Lanthanides in molecular magnetism: so fascinating, so challenging, M . A Co mplete Active Space SCF Method (CASSCF) Using a Density Matrix Formulated Super- CI Approach, pp.532-553, 1980.

P. Å. Malmqvist, B. O. Roos, and B. Schimmelpfennig, The restricted active space (RAS) state interaction approach with spin???orbit coupling, Chemical Physics Letters, vol.357, issue.3-4, pp.230-240, 2002.
DOI : 10.1016/S0009-2614(02)00498-0

B. O. Roos, R. Lindh, P. Malmqv-ist, V. Veryazov, and B. O. Roos, Main Group Atoms and Dimers Studied with a New Relativistic ANO Basis Set, The Journal of Physical Chemistry A, vol.108, issue.15, pp.2851-2858, 2004.
DOI : 10.1021/jp031064+

R. Lindh, P. Malmqvist, V. Veryazov, and P. Id-mark, New Re lativistic A NO Basis Sets for Transition Meta l Ato ms, J. Phys.Chem. A, vol.109, pp.6575-6579, 2005.

L. F. Chibotaru, L. Ungur, and L. F. Ch-ibotaru, Ab init io calculation of anisotropic magnetic properties of comp lexes. I. Unique defin ition of pseudospin Ha miltonians and their derivation, J. Chem. Phys. Adv. Chem. Phys, vol.137, issue.25 064112, pp.397-519, 2012.

F. Aquilante, J. Autschbach, and R. K. Carlson, Ch ibotaru

M. G. Delcey and L. De-vico, Fdez. Galván, I.; Ferré, N.; Frutos, L. M

L. Gagliardi, M. Garavelli, A. Giussani, C. E. Hoyer, and G. Li-manni,

H. Lischka, D. Ma, P. Å. Malmqv-ist, T. Müller, A. Nenov et al.,

I. Rivalta and I. Schapiro, Segarra-Martí, J.; Stenrup, M.; Truhlar, D. G

L. Ungur, A. Valentin-i, S. Vancoillie, V. Veryazov, and V. P. Vysotskiy,

O. Weingart, F. Zapata, and R. Lindh, Mo lcas 8: New capabilities for mu lticonfigurational quantum chemical calculat ions across the periodic table, J. Comput. Chem, vol.37, pp.506-541, 2016.

A. Ruiz-martínez, D. Casanova, and S. Alvarez, Polyhedral Structures with an Odd Nu mber of Vertices: Nine-Coordinate Metal Co mpounds

, Chem. ? Eur. J, vol.14, pp.1291-1303, 2008.

L. Sorace, C. Benelli, D. Gatteschi, J. Lanthanides-in-mo-lecular-magnetism-wu, X. Li et al., Enhancement of Magnetocaloric Effect through Fixation of Carbon Dio xide: Molecular Assembly fro m Ln 4 to Ln 4 Cluster Pairs A xial Ligand Field in D 4d Coordination Sy mmetry : Magnetic Relaxat ion of Dy SMMs Perturbed by Counteranions Introduction to molecular magnetism: From transition metals to lanthanides Chem, Large Spin- Relaxation Barriers for the Low-Sy mmetry Organolanthanide Comp lexes [Cp* 2 Ln(BPh 4 )] (Cp*=pentamethylcyclopentadienyl, pp.3092-3104, 2011.

?. J. Eur, J. Long, B. G. Shestakov, D. Liu, L. F. Chibotaru et al., An Organolanthanide(III) Single-Mo lecule Magnet with an Axial Crystal-Fie ld: Influence of the Raman Process over the Slow Relaxation, Chem. Commun, vol.20, issue.5332, pp.9524-9529, 2014.

S. Jiang, Z. Wang, Z. Ouyang, L. Deng, B. Wang et al., Two-Coordinate Co(II) Imido Co mplexes as Outstanding Single- Molecule Magnets Improv ing f-element Single Molecu le Magnets Strategies toward High-Temperature Lanthanide-Based Single-Molecule Magnets Experimental and Theoretical Interpretation on the Magnetic Behavior in a Series of Pentagonal-Bipyramidal Dy III Single-Ion Magnets, 37) Chibotaru, L. F. In Molecular Nanomagnets and Related Phenomena, pp.373-380, 1970.

S. Gao, E. Liu, J. Chen, Y. Liu, J. Vieru et al., A Stable Pentagonal Bipyramidal Dy(III) Single-Ion Magnet with a Record Magnetization Reversal Barrier over 1000 K, Ligand Field Fine-tuning on the Modulation of the Magnetic Properties and Relaxat ion Dynamics of Dysprosium(III) Single -Ion Magnets (SIMs): synthesis, structure, magnetism and Ab Init io Calculations, pp.185-229, 2015.
URL : https://hal.archives-ouvertes.fr/hal-01971368