, Applications to Synthesis of Biologically Active Compounds, J. Am. Chem. Soc, vol.2017, issue.139, pp.10919-10928

D. V. Peryshkov, R. R. Schrock, M. K. Takase, P. Müller, A. H. Hoveyda et al., -Selective Olefin Metathesis Reactions Promoted by Tungsten Oxo Alkylidene Complexes, Journal of the American Chemical Society, vol.133, issue.51, pp.20754-20757, 2009.
DOI : 10.1021/ja210349m

J. K. Lam, C. Zhu, K. V. Bukhryakov, P. Müller, A. H. Hoveyda et al., Synthesis and Evaluation of Molybdenum and Tungsten Monoaryloxide Halide Alkylidene Complexes for Z- Selective Cross-Metathesis of Cyclooctene and Z-1,2- Dichloroethylene Synthesis of Z-(Pinacolato)allylboron and Z(Pinacolato )alkenylboron Compounds through Stereoselective Catalytic Cross-Metathesis, For selected examples with Molybdenum-based complexesSelective Metathesis Homocoupling of 1,3-Dienes by Molybdenum and Tungsten Monoaryloxide Pyrrolide (MAP) Complexes, pp.15774-15783

R. R. Schrock and A. H. Hoveyda, Enol Ethers as Substrates for Efficient Z-and Enantioselective Ring-Opening/Cross-Metathesis Reactions Promoted by Stereogenic-at-Mo Complexes: Utility in Chemical Synthesis and Mechanistic Attributes, J. Am. Chem. Soc, vol.134, pp.2012-2788

P. Queval, E. Borré, and L. Falivene,

M. Berthod, F. Hugues, L. Cavallo, O. Baslé, H. Olivier-bourbigou et al., Selective Metathesis of ?-Olefins from Bio-Sourced Fischer-Tropsch Feeds, Verpoort, F. Olefin metathesis ruthenium catalysts bearing unsymmetrical heterocyclic carbenes. Coord. Chem, pp.7970-7976
URL : https://hal.archives-ouvertes.fr/hal-01558324

J. Revc-)-tornatzky, A. Kannenberg, and S. Blechert, New catalysts with unsymmetrical N-heterocyclic carbene ligands, Dalton Transactions, vol.75, issue.27, pp.2274-2292, 2013.
DOI : 10.1021/jo101147p

K. Endo and R. H. Grubbs, -Selective Olefin Metathesis, Journal of the American Chemical Society, vol.133, issue.22, pp.8525-8527, 2011.
DOI : 10.1021/ja202818v

B. K. Keitz, K. Endo, P. R. Patel, M. B. Herbert, R. H. Grubbs et al., Improved Ruthenium Catalysts for Z-Selective Olefin Metathesis in Olefin Metathesis with Chelated Ru Catalysts: Computational Studies of Mechanism and Selectivity, J. Am. Chem. Soc. J. Am. Chem. Soc, vol.2012, issue.134, pp.693-699, 2012.

R. H. Grubbs, Stereoselective Access to Z and E Macrocycles by Ruthenium-Catalyzed Z-Selective Ring-Closing Metathesis and Ethenolysis, J. Am. Chem. Soc, vol.135, pp.94-97, 2013.

T. S. Ahmed and R. H. Grubbs, Z-Selective ruthenium metathesis catalysts: Comparison of nitrate and nitrite X-type ligands, Polyhedron, vol.84, pp.144-149, 2014.

M. B. Herbert, R. H. Grubbs, L. E. Rosebrugh, M. B. Herbert, V. M. Marx et al., -Selective Cross Metathesis with Ruthenium Catalysts: Synthetic Applications and Mechanistic Implications, Angewandte Chemie International Edition, vol.125, issue.17, pp.5018-5024, 2013.
DOI : 10.1002/ange.201302724

L. E. Rosebrugh, T. S. Ahmed, V. M. Marx, J. Hartung, P. Liu et al., Probing Stereoselectivity in Ring-Opening Metathesis Polymerization Mediated by Cyclometalated Ruthenium-Based Catalysts: A Combined Experimental and Computational Study, Journal of the American Chemical Society, vol.138, issue.4, pp.1394-1405, 2016.
DOI : 10.1021/jacs.5b12277

URL : https://authors.library.caltech.edu/63767/2/ja5b12277_si_001.pdf

M. B. Herbert, Y. Lan, B. K. Keitz, P. Liu, K. Endo et al., -Selective Ruthenium Metathesis Catalysts, Journal of the American Chemical Society, vol.134, issue.18, pp.7861-7866
DOI : 10.1021/ja301108m

V. Dorcet, C. Crévisy, O. Baslé, and M. Mauduit, Readily Accessible Unsymmetrical Unsaturated 2,6-Diisopropylphenyl N-Heterocyclic Carbene Ligands Applications in Enantioselective Catalysis, J. Org. Chem, vol.2017, issue.82, pp.1880-1887
URL : https://hal.archives-ouvertes.fr/hal-01475697

I. Artur, J. Legeay, L. Falivene, L. Toupet, C. Crévisy et al., Multicomponent Synthesis of Unsymmetrical Unsaturated N-Heterocyclic Carbene Precursors and Their Related Transition-Metal Complexes Cyclometalated Z-Selective Ruthenium Metathesis Catalysts with Modified N-Chelating Groups Carboxylate-Assisted C(sp 3 )?H Activation in Olefin Metathesis-Relevant Ruthenium Complexes (19) (a) For a recent paper regarding selective metathesis with ?olefins , see reference (9a). (b) See supporting information for details Nitro- Grela-type complexes containing iodides ? robust and selective catalysts for olefin metathesis under challenging conditions, Investigations into Ruthenium Metathesis Catalysts with Six-Membered Chelating NHC Ligands: Relationship between Catalyst Structure and Stereoselectivity. P. Insights into the Decomposition of Olefin Metathesis Precatalysts E. Isomerization During Olefin Metathesis: An Assessment of Potential Catalyst Culprits. Chem- CatChem 2013, pp.14103-14107, 2013.

J. M. Bates, D. E. Fogg, S. M. Bronner, M. B. Herbert, P. R. Patel et al., Ru-based Z-selective metathesis catalysts with modified cyclometalated carbene ligands Ruthenium-Catalyzed One-Pot Synthesis of (E)-(2- Arylvinyl)boronates through an Isomerization/Cross-Metathesis Sequence from Allyl-Substituted Aromatics Synthesis of Alkenyl Boronates from Allyl-Substituted Aromatics Using an Olefin Cross-Metathesis Protocol Synthesis of Functionalized Vinyl Boronates via Ruthenium-Catalyzed Olefin Cross-Metathesis and Subsequent Conversion to Vinyl Halides Ruthenium-catalysed Zselective cross-metathesis of allylic-substituted olefins Synthesis of Z(Pinacolato )allylboron and Z-(Pinacolato)alkenylboron Compounds through Stereoselective Catalytic Cross-Metathesis, Reactions of Grubbs Catalysts with Excess Methoxide: Formation of Novel Methoxyhydride Complexes Grubbs, R. H. Concise Syntheses of Insect Pheromones Using Z-Selective Cross Metathesis The synthesis of the disparlure pheromone 15 is described in the supporting information. (26) (a) Cannon, J. S.; Grubbs, R. H. Alkene Chemoselectivity in Ruthenium-Catalyzed Z-Selective Olefin Metathesis. Angew. Chem, pp.2349-2356, 2003.

. Int and . Ed, (b) With conjugated dienes, see, pp.9001-9004, 2013.

R. H. Grubbs, Z-Selective Cross-Metathesis and Homodimerization of 3E-1,3-Dienes: Reaction Optimization, Computational Analysis, and Synthetic Applications, J. Am. Chem. Soc, vol.138, pp.14039-14046, 2016.

M. S. Mikus, S. Torker, A. H. Hoveyda, L. E. Rosebrugh, V. M. Marx et al., Controllable ROMP Tacticity by Harnessing the Fluxionality of Stereogenic-at-Ruthenium Complexes, Angewandte Chemie International Edition, vol.138, issue.16, pp.4997-5002, 2016.
DOI : 10.1021/jacs.5b12277

S. Keitz, B. K. Fedorov, A. Grubbs, and R. H. , Cis-Selective Ring-Opening Metathesis Polymerization with Ruthenium Catalysts, Journal of the American Chemical Society, vol.134, issue.4, pp.10032-10035, 2013.
DOI : 10.1021/ja211676y

URL : http://europepmc.org/articles/pmc3278323?pdf=render

L. Falivene, R. Credendino, A. Poater, A. Petta, L. Serra et al., SambVca 2. A Web Tool for Analyzing Catalytic Pockets with Topographic Steric Maps, Schrock, R. R. Z-Selective and Syndioselective Ring-Opening Metathesis Polymerization (ROMP) Initiated by Monoaryloxidepyrrolide (MAP) Catalysts. Macromolecules, pp.2286-2293, 2010.
DOI : 10.1021/acs.organomet.6b00371

URL : http://doi.org/10.1021/acs.organomet.6b00371