). D. Valyaev, G. Lavigne, and N. Lugan, Manganese organometallic compounds in homogeneous catalysis: Past, present, and prospects, Kallmeier and R. Kempe, Angew. Chem, pp.191-235, 2016.
DOI : 10.1016/j.ccr.2015.06.015
URL : https://hal.archives-ouvertes.fr/hal-01925253

. Int, G. A. Ed, R. Filonenko, and E. J. Van-putten, , pp.46-60, 2018.

E. A. Hensen and . Pidko, Chem. Soc. Rev, vol.47, pp.1459-1483, 2018.

Y. Li, X. Hu, and . Wu, Non-noble metal-catalysed carbonylative transformations, Chemical Society Reviews, vol.3, issue.95, pp.172-194, 2018.
DOI : 10.1021/cs300725j

S. Elangovan, C. Topf, S. Fischer, H. Jiao, A. Spannenberg et al., Selective Catalytic Hydrogenations of Nitriles, Ketones, and Aldehydes by Well-Defined Manganese Pincer Complexes, Dietel and R, pp.8809-8814, 2016.
DOI : 10.1021/jacs.6b03709

. Kempe, Angew. Chem. Int. Ed, vol.55, pp.11806-11809, 2016.

D. Bruneau-voisine, T. Wang, C. Roisnel, J. Darcel, and . Sortais, Catal. Commun. Angew. Chem. Int. Ed, vol.92, issue.56, pp.1-4, 2017.

). S. Elangovan, M. Garbe, H. Jiao, A. Spannenberg, K. Junge et al., Hydrogenation of Esters to Alcohols Catalyzed by Defined Manganese Pincer Complexes, Angewandte Chemie International Edition, vol.6, issue.49, pp.15364-15368, 2016.
DOI : 10.1038/ncomms7540

A. Espinosa-jalapa, A. Nerush, L. J. Shimon, and G. ,

Y. Avram, D. Ben-david, . M. Milsteinc-)-c, R. Kelly, O. L. Mcdonald et al., Chem. Eur. J. Angew. Chem. Int. Ed. Angew. Chem. Int. Ed, vol.23, issue.56, pp.5934-5938, 2017.

V. Papa, J. R. Cabrero-antonino, and E. Alberico,

H. Junge, M. Junge, and . Beller, Chem. Sci, vol.8, pp.3576-3585, 2017.

S. Kar, A. Goeppert, J. Kothandaraman, and G. K. Prakash, , pp.6347-6351, 2017.

C. Fayzullin, J. R. Nervi, and . Khusnutdinova, , pp.3864-3868, 2017.

L. F. Peruzzini, K. Veiros, L. Kirchner, and . Gonsalvi, Chem. Sci, vol.8, pp.5024-5029, 2017.

). M. Perez, S. Elangovan, A. Spannenberg, K. Junge, and M. ,

C. Beller, , pp.83-86, 2017.

V. Wang, T. Dorcet, C. Roisnel, J. Darcel, and . Sortais, Org. Lett, vol.19, pp.3656-3659, 2017.

A. Zirakzadeh, S. R. De-aguiar, B. Stöger, M. Widhalm, K. Kirchner et al., Catal. Commun. Angew. Chem. Int. Ed, vol.9, issue.56, pp.1744-1748, 2017.

A. Mukherjee, G. Nerush, L. J. Leitus, Y. B. Shimon, N. A. David et al., : A Catalytic and Mechanistic Study, Journal of the American Chemical Society, vol.138, issue.13, pp.4298-4301, 2016.
DOI : 10.1021/jacs.5b13519

E. Stöger, G. Pittenauer, L. F. Allmaier, K. Veiros, and . Kirchner, Chem. Eur. J. Angew. Chem. Int. Ed, vol.22, pp.12316-12320, 2016.

D. H. Nguyen, X. Trivelli, F. Capet, J. Paul, F. Dumeignil et al., Angew. Chem. Int. Ed. J. Am. Chem. Soc. Angew. Chem. Int. Ed, vol.56, issue.56, pp.4229-4233, 2017.

M. Peña?lópez, P. Piehl, S. Elangovan, H. Neumann, and M. Beller, Manganese-Catalyzed Hydrogen-Autotransfer C???C Bond Formation: ??-Alkylation of Ketones with Primary Alcohols, Angewandte Chemie International Edition, vol.132, issue.48, pp.14967-14971, 2016.
DOI : 10.1021/ja1080019

S. Chakraborty, U. K. Das, Y. Ben-david, and D. Milstein, Manganese Catalyzed ??-Olefination of Nitriles by Primary Alcohols, Journal of the American Chemical Society, vol.139, issue.34, pp.11710-11713, 2017.
DOI : 10.1021/jacs.7b06993

S. Fu, Z. Shao, Y. Wang, and Q. Liu, Manganese-Catalyzed Upgrading of Ethanol into 1-Butanol, Journal of the American Chemical Society, vol.139, issue.34, pp.11941-11948, 2017.
DOI : 10.1021/jacs.7b05939

M. Andérez?fernández, L. K. Vogt, S. Fischer, W. Zhou, H. Jiao et al., A Stable Manganese Pincer Catalyst for the Selective Dehydrogenation of Methanol, Angewandte Chemie International Edition, vol.7, issue.2, pp.559-562, 2017.
DOI : 10.1002/cctc.201402716

J. O. Bauer, S. Chakraborty, and D. Milstein, Manganese-Catalyzed Direct Deoxygenation of Primary Alcohols, ACS Catalysis, vol.7, issue.7, pp.4462-4466, 2017.
DOI : 10.1021/acscatal.7b01729

S. Elangovan, J. Neumann, J. Sortais, K. Junge, C. Darcel et al., Nat. Commun. J. Catal. Chem. Eur. J, vol.347, issue.23, pp.57-62, 2016.

M. Mastalir, E. Pittenauer, G. Allmaier, and K. Kirchner, Manganese-Catalyzed Aminomethylation of Aromatic Compounds with Methanol as a Sustainable C1 Building Block, Journal of the American Chemical Society, vol.139, issue.26, pp.8812-8815, 2017.
DOI : 10.1021/jacs.7b05253

M. Mastalir, M. Glatz, E. Pittenauer, G. Allmaier, and K. Kirchner, Sustainable Synthesis of Quinolines and Pyrimidines Catalyzed by Manganese PNP Pincer Complexes, Journal of the American Chemical Society, vol.138, issue.48, pp.15543-15546, 2016.
DOI : 10.1021/jacs.6b10433

F. Kallmeier, B. Dudziec, T. Irrgang, and R. Kempe, Manganese-Catalyzed Sustainable Synthesis of Pyrroles from Alcohols and Amino Alcohols, Angewandte Chemie International Edition, vol.128, issue.25, pp.7261-7265, 2017.
DOI : 10.1002/chem.201701211

N. Deibl and R. Kempe, Manganese-Catalyzed Multicomponent Synthesis of Pyrimidines from Alcohols and Amidines, Angewandte Chemie International Edition, vol.126, issue.6, pp.1663-1666, 2017.
DOI : 10.1002/ange.201307950

S. Gomez, J. A. Peters, T. Maschmeyer, A. Synth, B. Catal et al., Amines: synthesis, properties and applications, Misal Castro, J.-B. Sortais and C. Darcel, pp.1037-1057, 2002.

P. Bheeter, M. Henrion, M. J. Chetcuti, C. Darcel, V. Ritleng et al., Catal. Sci. Technol. ChemCatChem Chem. Commun, vol.3, issue.50, pp.3111-3116, 2013.

D. Wei, A. Bruneau-voisine, T. Chauvin, V. Dorcet, T. Roisnel et al., Hydrogenation of Carbonyl Derivatives Catalysed by Manganese Complexes Bearing Bidentate Pyridinyl-Phosphine Ligands, Advanced Synthesis & Catalysis, vol.23, issue.4, pp.676-681, 2018.
DOI : 10.1016/j.tetasy.2012.05.019
URL : https://hal.archives-ouvertes.fr/hal-01737372

, Ketimines are not reduced under these conditions, see Table S5 in SI

M. Ishihara and H. Togo, Direct oxidative conversion of aldehydes and alcohols to 2-imidazolines and 2-oxazolines using molecular iodine, Tetrahedron, vol.63, issue.6, pp.1474-1480, 2007.
DOI : 10.1016/j.tet.2006.11.077

, Under standard conditions, c.a. 10% of unsatured amine d40' was identified in the crude mixture